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Controlled Ring-Opening Metathesis Polymerization with Polyisobutylene-Bound Pyridine-Ligated Ru(II) Catalysts

[Image: see text] This study describes the use of polyisobutylene (PIB) to phase-anchor pyridine ligands that form a phase-separable Grubbs third-generation catalyst. We further show that this complex is useful in ring-opening metathesis polymerization (ROMP) reactions. These PIB-bound pyridine-liga...

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Detalles Bibliográficos
Autores principales: Suriboot, Jakkrit, Hu, Yue, Malinski, Thomas J., Bazzi, Hassan S., Bergbreiter, David E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6640752/
https://www.ncbi.nlm.nih.gov/pubmed/31457158
http://dx.doi.org/10.1021/acsomega.6b00218