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Synthesis of 2-Arylimino-6,7-dihydrobenzo[d][1,3]oxathiol-4(5H)-ones via Rh(2)(OAc)(4)-Catalyzed Reactions of Cyclic 2-Diazo-1,3-diketones with Aryl Isothiocyanates

[Image: see text] A convenient and efficient synthesis of 2-arylimino-6,7-dihydrobenzo[d][1,3]oxathiol-4(5H)-ones was developed via a Rh(2)(OAc)(4)-catalyzed reaction of cyclic 2-diazo-1,3-diketones and aryl isothiocyanates in acetone at 60 °C. This reaction uses readily available stable cyclic 2-di...

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Detalles Bibliográficos
Autores principales: He, Xinwei, Zhou, Yao, Shang, Yongjia, Yang, Cheng, Zuo, Youpeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6640800/
https://www.ncbi.nlm.nih.gov/pubmed/31457195
http://dx.doi.org/10.1021/acsomega.6b00295

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