Sultam-Based Hetero[5]helicene: Synthesis, Structure, and Crystallization-Induced Emission Enhancement

[Image: see text] A deep-blue-emitting sultam-based hetero[5]helicene was synthesized in four steps, and its crystal structure and physical properties were characterized. The helicene displays more than two-fold crystallization-induced emission enhancement as well as atypical blue-shifting of its solid-state emission relative to the solution phase. This rapid synthesis of an unusual sulfonamide-based helicene fluorophore is expected to generate new molecular design options that will help address the ongoing challenges associated with designing pure-blue emitters for organic optoelectronic and sensing applications.