Cargando…

Palladium-Catalyzed Cascade Wacker/Allylation Sequence with Allylic Alcohols Leading to Allylated Dihydropyrones

[Image: see text] We describe a cascade Wacker/allylation sequence of β-hydroxy ynones by directly using simple allylic alcohols. This palladium(II)-catalyzed reaction occurs under mild conditions (0 °C to room temperature) and provides a new and efficient synthetic method for the preparation of all...

Descripción completa

Detalles Bibliográficos
Autores principales:	Huang, Wen-Yu, Nishikawa, Toshio, Nakazaki, Atsuo
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2017
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6640993/ https://www.ncbi.nlm.nih.gov/pubmed/31457451 http://dx.doi.org/10.1021/acsomega.7b00028

Ejemplares similares

Palladium-Catalyzed Allylation/Benzylation of H-Phosphinate Esters with Alcohols
por: Fers-Lidou, Anthony, et al.
Publicado: (2016)

Copper-Catalyzed Enantioselective Borylative Allyl–Allyl Coupling of Allenes and Allylic gem-Dichlorides
por: Piñeiro-Suárez, Martín, et al.
Publicado: (2023)

Nickel-catalyzed enantioselective allylic alkylation of lactones and lactams with unactivated allylic alcohols
por: Ngamnithiporn, Aurapat, et al.
Publicado: (2018)

Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones
por: Craig, Robert A., et al.
Publicado: (2015)

Platinum-Catalyzed Allylation of 2,3-Disubstituted Indoles with Allylic Acetates
por: Peng, Bai-Jing, et al.
Publicado: (2017)

Palladium-catalyzed allylic etherification of phenols with vinyl ethylene carbonate
por: Lin, Shibo, et al.
Publicado: (2022)

Dehydration in water: frustrated Lewis pairs directly catalyzed allylization of electron-rich arenes and allyl alcohols
por: Zhang, Hua, et al.
Publicado: (2020)

Catalytic Stereospecific Allyl–Allyl Cross-Coupling of Internal Allyl Electrophiles with AllylB(pin)
por: Le, Hai, et al.
Publicado: (2014)

Carboxylate-directed C–H allylation with allyl alcohols or ethers
por: Hu, Xiao-Qiang, et al.
Publicado: (2018)

Palladium Catalyzed Allylic C-H Alkylation: A Mechanistic Perspective
por: Engelin, Casper Junker, et al.
Publicado: (2011)

Palladium-catalyzed asymmetric allylic alkylation (AAA) with alkyl sulfones as nucleophiles
por: Trost, Barry M., et al.
Publicado: (2021)

The role of allyl ammonium salts in palladium-catalyzed cascade reactions towards the synthesis of spiro-fused heterocycles
por: Ye, Fei, et al.
Publicado: (2020)

Equilibrium Study of Pd(dba)(2) and P(OPh)(3) in the Pd-Catalyzed Allylation of Aniline by Allyl Alcohol
por: Sawadjoon, Supaporn, et al.
Publicado: (2013)

Enantioselective and site-specific copper-catalyzed reductive allyl–allyl cross-coupling of allenes
por: Xu, Guoxing, et al.
Publicado: (2018)

Regioselective molybdenum-catalyzed allylic substitution of tertiary allylic electrophiles: methodology development and applications
por: Salman, Muhammad, et al.
Publicado: (2020)

Palladium-catalyzed tandem allylic substitution/cyclization and cascade hydrosilylated reduction: the influence of reaction parameters and hydrosilanes on the stereoselectivity
por: Long, Peng-Wei, et al.
Publicado: (2018)

Enantioselective construction of C-chiral allylic sulfilimines via the iridium-catalyzed allylic amination with S,S-diphenylsulfilimine: asymmetric synthesis of primary allylic amines
por: Grange, Rebecca L., et al.
Publicado: (2015)

Palladium-catalyzed cross-coupling of α-bromocarbonyls and allylic alcohols for the synthesis of α-aryl dicarbonyl compounds
por: Yu, Yang, et al.
Publicado: (2015)

Electronic differentiation competes with transition state sensitivity in palladium-catalyzed allylic substitutions
por: Lange, Dominik A, et al.
Publicado: (2007)

Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Thietane 1,1-Dioxides
por: Laidlaw, Gillian, et al.
Publicado: (2021)

Palladium-catalyzed asymmetric allylic 4-pyridinylation via electroreductive substitution reaction
por: Ding, Weijie, et al.
Publicado: (2022)

Effective synthesis of bicyclodienes via palladium-catalyzed asymmetric allylic alkylation and ruthenium-catalyzed cycloisomerization
por: HAVARE, Nizam
Publicado: (2020)

Palladium-catalyzed regio- and enantioselective migratory allylic C(sp(3))-H functionalization
por: Chen, Ye-Wei, et al.
Publicado: (2021)

Pd-catalyzed asymmetric allylic alkylations via C–H activation of N-allyl imines with glycinates
por: Trost, Barry M., et al.
Publicado: (2017)

Highly Enantioselective Hiyama Cross-Coupling via Rh-Catalyzed Allylic Arylation of Racemic Allyl Chlorides
por: González, Jesús, et al.
Publicado: (2019)

An investigation of the allylation cascade reactions of substituted indigos
por: Perry, Matthew J., et al.
Publicado: (2023)

Copper-catalyzed asymmetric allylic alkylation of racemic inert cyclic allylic ethers under batch and flow conditions
por: Li, Jun, et al.
Publicado: (2023)

Enantioselective Construction of Quaternary N-Heterocycles by Palladium-Catalyzed Decarboxylative Allylic Alkylation of Lactams
por: Behenna, Douglas C., et al.
Publicado: (2011)

Iridium-catalyzed enantioselective alkynylation and kinetic resolution of alkyl allylic alcohols
por: Guo, Jia, et al.
Publicado: (2022)

Tungsten-Catalyzed Asymmetric Epoxidation of Allylic and Homoallylic Alcohols with Hydrogen Peroxide
por: Wang, Chuan, et al.
Publicado: (2014)

Iridium-Catalyzed 1,3-Hydrogen Shift/Chlorination of Allylic Alcohols**
por: Ahlsten, Nanna, et al.
Publicado: (2013)

Pressure Dependent Product Formation in the Photochemically Initiated Allyl + Allyl Reaction
por: Seidel, Lars, et al.
Publicado: (2013)

A straightforward and convenient synthesis of functionalized allyl thiosulfonates and allyl disulfanes
por: Reddy, Raju Jannapu, et al.
Publicado: (2018)

Allylic Alkylations Catalyzed By Palladium-Bis(oxazoline) Complexes Derived From Heteroarylidene Malonate Derivatives
por: Liu, Lei, et al.
Publicado: (2012)

Development of β -keto ester and malonate chemistry: Palladium-catalyzed new reactions of their allylic esters
por: Tsuji, Jiro
Publicado: (2004)

Influence of Achiral Phosphine Ligands on a Synergistic Organo‐ and Palladium‐Catalyzed Asymmetric Allylic Alkylation
por: McLeod, David, et al.
Publicado: (2022)

Palladium-catalysed 5-endo-trig allylic (hetero)arylation
por: Singh, Bara, et al.
Publicado: (2020)

Dual nickel and Lewis acid catalysis for cross-electrophile coupling: the allylation of aryl halides with allylic alcohols
por: Jia, Xue-Gong, et al.
Publicado: (2017)

The Sulfilimine Analogue of Allicin, S-Allyl-S-(S-allyl)-N-Cyanosulfilimine, Is Antimicrobial and Reacts with Glutathione
por: Horn, Tobias, et al.
Publicado: (2020)

Et(3)B-mediated and palladium-catalyzed direct allylation of β-dicarbonyl compounds with Morita–Baylis–Hillman alcohols
por: Abidi, Ahlem, et al.
Publicado: (2016)

Cannot write session to /tmp/vufind_sessions/sess_r8hs506otrl7drj775jp8mpvjg