Expanding the Scope of Electron-Deficient C–H Building Blocks: Direct Arylation of Pyromellitic Acid Diimide

[Image: see text] Direct C–H activation of pyromellitic diimide (PMDI) is reported for the first time. The method avoids cumbersome pathways involving bromination usually required for further cross-coupling. Good to excellent yields of mono- and di-substituted PMDI derivatives can be obtained under optimized reaction conditions. The reaction scope was also explored, and the materials were characterized with respect to their thermal, optical, and electronic properties.