Extending the Scope of a New Cyanation: Design and Synthesis of an Anthracene Derivative with an Exceptionally Low LUMO Level and Improved Solubility

[Image: see text] The preparation of cyanated acenes from quinones has been improved for the conversion of electron-poor starting materials. The new procedure was used to prepare rationally designed 2,7-dinitro-9,10-dicyanoanthracene. Crystallographic, morphological, and electrochemical investigatio...

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Autores principales: Glöcklhofer, Florian, Morawietz, Andreas J., Stöger, Berthold, Unterlass, Miriam M., Fröhlich, Johannes
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641058/
https://www.ncbi.nlm.nih.gov/pubmed/31457525
http://dx.doi.org/10.1021/acsomega.7b00245
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author Glöcklhofer, Florian
Morawietz, Andreas J.
Stöger, Berthold
Unterlass, Miriam M.
Fröhlich, Johannes
author_facet Glöcklhofer, Florian
Morawietz, Andreas J.
Stöger, Berthold
Unterlass, Miriam M.
Fröhlich, Johannes
author_sort Glöcklhofer, Florian
collection PubMed
description [Image: see text] The preparation of cyanated acenes from quinones has been improved for the conversion of electron-poor starting materials. The new procedure was used to prepare rationally designed 2,7-dinitro-9,10-dicyanoanthracene. Crystallographic, morphological, and electrochemical investigations have revealed most promising properties for applications in organic electronics.
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spelling pubmed-66410582019-08-27 Extending the Scope of a New Cyanation: Design and Synthesis of an Anthracene Derivative with an Exceptionally Low LUMO Level and Improved Solubility Glöcklhofer, Florian Morawietz, Andreas J. Stöger, Berthold Unterlass, Miriam M. Fröhlich, Johannes ACS Omega [Image: see text] The preparation of cyanated acenes from quinones has been improved for the conversion of electron-poor starting materials. The new procedure was used to prepare rationally designed 2,7-dinitro-9,10-dicyanoanthracene. Crystallographic, morphological, and electrochemical investigations have revealed most promising properties for applications in organic electronics. American Chemical Society 2017-04-24 /pmc/articles/PMC6641058/ /pubmed/31457525 http://dx.doi.org/10.1021/acsomega.7b00245 Text en Copyright © 2017 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
spellingShingle Glöcklhofer, Florian
Morawietz, Andreas J.
Stöger, Berthold
Unterlass, Miriam M.
Fröhlich, Johannes
Extending the Scope of a New Cyanation: Design and Synthesis of an Anthracene Derivative with an Exceptionally Low LUMO Level and Improved Solubility
title Extending the Scope of a New Cyanation: Design and Synthesis of an Anthracene Derivative with an Exceptionally Low LUMO Level and Improved Solubility
title_full Extending the Scope of a New Cyanation: Design and Synthesis of an Anthracene Derivative with an Exceptionally Low LUMO Level and Improved Solubility
title_fullStr Extending the Scope of a New Cyanation: Design and Synthesis of an Anthracene Derivative with an Exceptionally Low LUMO Level and Improved Solubility
title_full_unstemmed Extending the Scope of a New Cyanation: Design and Synthesis of an Anthracene Derivative with an Exceptionally Low LUMO Level and Improved Solubility
title_short Extending the Scope of a New Cyanation: Design and Synthesis of an Anthracene Derivative with an Exceptionally Low LUMO Level and Improved Solubility
title_sort extending the scope of a new cyanation: design and synthesis of an anthracene derivative with an exceptionally low lumo level and improved solubility
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641058/
https://www.ncbi.nlm.nih.gov/pubmed/31457525
http://dx.doi.org/10.1021/acsomega.7b00245
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