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Convenient Synthesis of Deuterosilanes by Direct H/D Exchange Mediated by Easily Accessible Pt(0) Complexes
[Image: see text] Easily accessible, simple phosphino-platinum(0) complexes catalyze (0.1–1 mol % equivalent) the deuteration of silanes in good yields under mild conditions (60 °C, 1 atm). The catalysis is mediated by platinum(II) deuteride/hydride complexes that are in equilibrium with the precurs...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641072/ https://www.ncbi.nlm.nih.gov/pubmed/31457444 http://dx.doi.org/10.1021/acsomega.6b00401 |