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Convenient Synthesis of Deuterosilanes by Direct H/D Exchange Mediated by Easily Accessible Pt(0) Complexes

[Image: see text] Easily accessible, simple phosphino-platinum(0) complexes catalyze (0.1–1 mol % equivalent) the deuteration of silanes in good yields under mild conditions (60 °C, 1 atm). The catalysis is mediated by platinum(II) deuteride/hydride complexes that are in equilibrium with the precurs...

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Detalles Bibliográficos
Autores principales:	Kratish, Yosi, Bravo-Zhivotovskii, Dmitry, Apeloig, Yitzhak
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2017
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641072/ https://www.ncbi.nlm.nih.gov/pubmed/31457444 http://dx.doi.org/10.1021/acsomega.6b00401

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