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Immobilization of a Boron Center-Functionalized Scorpionate Ligand on Mesoporous Silica Supports for Heterogeneous Tp-Based Catalysts

[Image: see text] To develop novel immobilized metallocomplex catalysts, allyltris(3-trifluoromethylpyrazol-1-yl)borate (allyl-Tp(CF3)) was synthesized. A boron-attached allyl group reacts with thiol to afford the desired mesoporous silica-immobilized Tp(CF3). Cobalt(II) is an efficient probe for es...

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Detalles Bibliográficos
Autores principales:	Nakamizu, Ayaka, Kasai, Takeshi, Nakazawa, Jun, Hikichi, Shiro
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2017
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641073/ https://www.ncbi.nlm.nih.gov/pubmed/31457483 http://dx.doi.org/10.1021/acsomega.7b00022

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