Phenolacetyl Viologen as Multifunctional Chromic Material for Fast and Reversible Sensor of Solvents, Base, Temperature, Metal Ions, NH(3) Vapor, and Grind in Solution and Solid State

[Image: see text] Electron-withdrawing/coordinating o-phenolacetyl-substituted viologen can act as a visual sensor for solvents, bases, and temperature in organic solvents. Due to chelating phenolacetyl groups, this viologen can coordinate to Fe(III), Cu(II), and ZnCl(2) in aqueous and DMF solutions...

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Autores principales: Hu, Meiling, Xing, Feifei, Zhao, Yongmei, Bai, Yue-Ling, Li, Ming-Xing, Zhu, Shourong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641105/
https://www.ncbi.nlm.nih.gov/pubmed/31457495
http://dx.doi.org/10.1021/acsomega.7b00035
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author Hu, Meiling
Xing, Feifei
Zhao, Yongmei
Bai, Yue-Ling
Li, Ming-Xing
Zhu, Shourong
author_facet Hu, Meiling
Xing, Feifei
Zhao, Yongmei
Bai, Yue-Ling
Li, Ming-Xing
Zhu, Shourong
author_sort Hu, Meiling
collection PubMed
description [Image: see text] Electron-withdrawing/coordinating o-phenolacetyl-substituted viologen can act as a visual sensor for solvents, bases, and temperature in organic solvents. Due to chelating phenolacetyl groups, this viologen can coordinate to Fe(III), Cu(II), and ZnCl(2) in aqueous and DMF solutions. Interestingly, this viologen can respond to temperature, grind, and NH(3) vapor in its solid state. Stimuli response is visible, fast, and fully reversible in air at room temperature. The color change is attributed to the enolic and/or free radical structure. This is the most versatile chromic material that responds to chemical and physical stimuli in both solution and solid state.
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spelling pubmed-66411052019-08-27 Phenolacetyl Viologen as Multifunctional Chromic Material for Fast and Reversible Sensor of Solvents, Base, Temperature, Metal Ions, NH(3) Vapor, and Grind in Solution and Solid State Hu, Meiling Xing, Feifei Zhao, Yongmei Bai, Yue-Ling Li, Ming-Xing Zhu, Shourong ACS Omega [Image: see text] Electron-withdrawing/coordinating o-phenolacetyl-substituted viologen can act as a visual sensor for solvents, bases, and temperature in organic solvents. Due to chelating phenolacetyl groups, this viologen can coordinate to Fe(III), Cu(II), and ZnCl(2) in aqueous and DMF solutions. Interestingly, this viologen can respond to temperature, grind, and NH(3) vapor in its solid state. Stimuli response is visible, fast, and fully reversible in air at room temperature. The color change is attributed to the enolic and/or free radical structure. This is the most versatile chromic material that responds to chemical and physical stimuli in both solution and solid state. American Chemical Society 2017-03-22 /pmc/articles/PMC6641105/ /pubmed/31457495 http://dx.doi.org/10.1021/acsomega.7b00035 Text en Copyright © 2017 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Hu, Meiling
Xing, Feifei
Zhao, Yongmei
Bai, Yue-Ling
Li, Ming-Xing
Zhu, Shourong
Phenolacetyl Viologen as Multifunctional Chromic Material for Fast and Reversible Sensor of Solvents, Base, Temperature, Metal Ions, NH(3) Vapor, and Grind in Solution and Solid State
title Phenolacetyl Viologen as Multifunctional Chromic Material for Fast and Reversible Sensor of Solvents, Base, Temperature, Metal Ions, NH(3) Vapor, and Grind in Solution and Solid State
title_full Phenolacetyl Viologen as Multifunctional Chromic Material for Fast and Reversible Sensor of Solvents, Base, Temperature, Metal Ions, NH(3) Vapor, and Grind in Solution and Solid State
title_fullStr Phenolacetyl Viologen as Multifunctional Chromic Material for Fast and Reversible Sensor of Solvents, Base, Temperature, Metal Ions, NH(3) Vapor, and Grind in Solution and Solid State
title_full_unstemmed Phenolacetyl Viologen as Multifunctional Chromic Material for Fast and Reversible Sensor of Solvents, Base, Temperature, Metal Ions, NH(3) Vapor, and Grind in Solution and Solid State
title_short Phenolacetyl Viologen as Multifunctional Chromic Material for Fast and Reversible Sensor of Solvents, Base, Temperature, Metal Ions, NH(3) Vapor, and Grind in Solution and Solid State
title_sort phenolacetyl viologen as multifunctional chromic material for fast and reversible sensor of solvents, base, temperature, metal ions, nh(3) vapor, and grind in solution and solid state
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641105/
https://www.ncbi.nlm.nih.gov/pubmed/31457495
http://dx.doi.org/10.1021/acsomega.7b00035
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