Formation of TbPc(2) Single-Molecule Magnets’ Covalent 1D Structures via Acyclic Diene Metathesis

[Image: see text] We present here a reaction scheme to connect TbPc(2) single-molecule magnets into 1D architectures using acyclic diene metathesis. To investigate the impact of the bonding through aliphatic chains on the magnetic properties of TbPc(2), we isolate and characterize the dimeric specie...

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Detalles Bibliográficos
Autores principales: Pedrini, Alessandro, Perfetti, Mauro, Mannini, Matteo, Dalcanale, Enrico
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641184/
https://www.ncbi.nlm.nih.gov/pubmed/31457452
http://dx.doi.org/10.1021/acsomega.6b00546
Descripción
Sumario:[Image: see text] We present here a reaction scheme to connect TbPc(2) single-molecule magnets into 1D architectures using acyclic diene metathesis. To investigate the impact of the bonding through aliphatic chains on the magnetic properties of TbPc(2), we isolate and characterize the dimeric species obtained as one of the products of the reaction. Remarkably, the magnetic properties are only slightly modified after the formation of the bond between molecules, enlightening the great potential of this reaction scheme.

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