Formation of TbPc(2) Single-Molecule Magnets’ Covalent 1D Structures via Acyclic Diene Metathesis

[Image: see text] We present here a reaction scheme to connect TbPc(2) single-molecule magnets into 1D architectures using acyclic diene metathesis. To investigate the impact of the bonding through aliphatic chains on the magnetic properties of TbPc(2), we isolate and characterize the dimeric specie...

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Autores principales: Pedrini, Alessandro, Perfetti, Mauro, Mannini, Matteo, Dalcanale, Enrico
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641184/
https://www.ncbi.nlm.nih.gov/pubmed/31457452
http://dx.doi.org/10.1021/acsomega.6b00546
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author Pedrini, Alessandro
Perfetti, Mauro
Mannini, Matteo
Dalcanale, Enrico
author_facet Pedrini, Alessandro
Perfetti, Mauro
Mannini, Matteo
Dalcanale, Enrico
author_sort Pedrini, Alessandro
collection PubMed
description [Image: see text] We present here a reaction scheme to connect TbPc(2) single-molecule magnets into 1D architectures using acyclic diene metathesis. To investigate the impact of the bonding through aliphatic chains on the magnetic properties of TbPc(2), we isolate and characterize the dimeric species obtained as one of the products of the reaction. Remarkably, the magnetic properties are only slightly modified after the formation of the bond between molecules, enlightening the great potential of this reaction scheme.
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spelling pubmed-66411842019-08-27 Formation of TbPc(2) Single-Molecule Magnets’ Covalent 1D Structures via Acyclic Diene Metathesis Pedrini, Alessandro Perfetti, Mauro Mannini, Matteo Dalcanale, Enrico ACS Omega [Image: see text] We present here a reaction scheme to connect TbPc(2) single-molecule magnets into 1D architectures using acyclic diene metathesis. To investigate the impact of the bonding through aliphatic chains on the magnetic properties of TbPc(2), we isolate and characterize the dimeric species obtained as one of the products of the reaction. Remarkably, the magnetic properties are only slightly modified after the formation of the bond between molecules, enlightening the great potential of this reaction scheme. American Chemical Society 2017-02-13 /pmc/articles/PMC6641184/ /pubmed/31457452 http://dx.doi.org/10.1021/acsomega.6b00546 Text en Copyright © 2017 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Pedrini, Alessandro
Perfetti, Mauro
Mannini, Matteo
Dalcanale, Enrico
Formation of TbPc(2) Single-Molecule Magnets’ Covalent 1D Structures via Acyclic Diene Metathesis
title Formation of TbPc(2) Single-Molecule Magnets’ Covalent 1D Structures via Acyclic Diene Metathesis
title_full Formation of TbPc(2) Single-Molecule Magnets’ Covalent 1D Structures via Acyclic Diene Metathesis
title_fullStr Formation of TbPc(2) Single-Molecule Magnets’ Covalent 1D Structures via Acyclic Diene Metathesis
title_full_unstemmed Formation of TbPc(2) Single-Molecule Magnets’ Covalent 1D Structures via Acyclic Diene Metathesis
title_short Formation of TbPc(2) Single-Molecule Magnets’ Covalent 1D Structures via Acyclic Diene Metathesis
title_sort formation of tbpc(2) single-molecule magnets’ covalent 1d structures via acyclic diene metathesis
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641184/
https://www.ncbi.nlm.nih.gov/pubmed/31457452
http://dx.doi.org/10.1021/acsomega.6b00546
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