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Pt/Co Alloy Nanoparticles Prepared by Nanocapsule Method Exhibit a High Oxygen Reduction Reaction Activity in the Alkaline Media
[Image: see text] Oxygen reduction reaction (ORR) catalysts are one of the main topics for fuel cells and metal/air batteries. We found that the platinum–cobalt alloy nanoparticles prepared by our original nanocapsule method exhibited a high ORR catalytic activity in alkaline solution, compared with...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2017
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641187/ https://www.ncbi.nlm.nih.gov/pubmed/31457562 http://dx.doi.org/10.1021/acsomega.7b00415 |
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author | Miyatake, Kenji Shimizu, Yuma |
author_facet | Miyatake, Kenji Shimizu, Yuma |
author_sort | Miyatake, Kenji |
collection | PubMed |
description | [Image: see text] Oxygen reduction reaction (ORR) catalysts are one of the main topics for fuel cells and metal/air batteries. We found that the platinum–cobalt alloy nanoparticles prepared by our original nanocapsule method exhibited a high ORR catalytic activity in alkaline solution, compared with that of the existing alloy nanoparticles prepared by different methods. The effect of alloy composition on the ORR activity was investigated to find the optimum composition (approximately 40 atom %). We also found that the enhancement of the catalytic activity in alkaline solution appeared in a very narrow range of Co content compared with that in acidic solution. |
format | Online Article Text |
id | pubmed-6641187 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-66411872019-08-27 Pt/Co Alloy Nanoparticles Prepared by Nanocapsule Method Exhibit a High Oxygen Reduction Reaction Activity in the Alkaline Media Miyatake, Kenji Shimizu, Yuma ACS Omega [Image: see text] Oxygen reduction reaction (ORR) catalysts are one of the main topics for fuel cells and metal/air batteries. We found that the platinum–cobalt alloy nanoparticles prepared by our original nanocapsule method exhibited a high ORR catalytic activity in alkaline solution, compared with that of the existing alloy nanoparticles prepared by different methods. The effect of alloy composition on the ORR activity was investigated to find the optimum composition (approximately 40 atom %). We also found that the enhancement of the catalytic activity in alkaline solution appeared in a very narrow range of Co content compared with that in acidic solution. American Chemical Society 2017-05-16 /pmc/articles/PMC6641187/ /pubmed/31457562 http://dx.doi.org/10.1021/acsomega.7b00415 Text en Copyright © 2017 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Miyatake, Kenji Shimizu, Yuma Pt/Co Alloy Nanoparticles Prepared by Nanocapsule Method Exhibit a High Oxygen Reduction Reaction Activity in the Alkaline Media |
title | Pt/Co Alloy Nanoparticles
Prepared by Nanocapsule Method Exhibit a High Oxygen
Reduction Reaction Activity in the Alkaline Media |
title_full | Pt/Co Alloy Nanoparticles
Prepared by Nanocapsule Method Exhibit a High Oxygen
Reduction Reaction Activity in the Alkaline Media |
title_fullStr | Pt/Co Alloy Nanoparticles
Prepared by Nanocapsule Method Exhibit a High Oxygen
Reduction Reaction Activity in the Alkaline Media |
title_full_unstemmed | Pt/Co Alloy Nanoparticles
Prepared by Nanocapsule Method Exhibit a High Oxygen
Reduction Reaction Activity in the Alkaline Media |
title_short | Pt/Co Alloy Nanoparticles
Prepared by Nanocapsule Method Exhibit a High Oxygen
Reduction Reaction Activity in the Alkaline Media |
title_sort | pt/co alloy nanoparticles
prepared by nanocapsule method exhibit a high oxygen
reduction reaction activity in the alkaline media |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641187/ https://www.ncbi.nlm.nih.gov/pubmed/31457562 http://dx.doi.org/10.1021/acsomega.7b00415 |
work_keys_str_mv | AT miyatakekenji ptcoalloynanoparticlespreparedbynanocapsulemethodexhibitahighoxygenreductionreactionactivityinthealkalinemedia AT shimizuyuma ptcoalloynanoparticlespreparedbynanocapsulemethodexhibitahighoxygenreductionreactionactivityinthealkalinemedia |