Unsubstituted Bambusurils: Post-Macrocyclization Modification of Versatile Intermediates

[Image: see text] A new bambusuril derivative, (H)BU[6], lacking substituents on the ureidic nitrogen atoms, has been isolated and characterized. This macrocycle was prepared by the deprotection of bambusuril (PMB)BU[6]. (H)BU[6] is attractive for use as a starting compound for the preparation of ot...

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Autores principales: Havel, Václav, Sadilová, Tereza, Šindelář, Vladimír
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641224/
https://www.ncbi.nlm.nih.gov/pubmed/31458686
http://dx.doi.org/10.1021/acsomega.8b00497
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author Havel, Václav
Sadilová, Tereza
Šindelář, Vladimír
author_facet Havel, Václav
Sadilová, Tereza
Šindelář, Vladimír
author_sort Havel, Václav
collection PubMed
description [Image: see text] A new bambusuril derivative, (H)BU[6], lacking substituents on the ureidic nitrogen atoms, has been isolated and characterized. This macrocycle was prepared by the deprotection of bambusuril (PMB)BU[6]. (H)BU[6] is attractive for use as a starting compound for the preparation of other bambusuril derivatives, which was demonstrated via propargylation and the copper-catalyzed click reaction performed on the macrocycle.
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spelling pubmed-66412242019-08-27 Unsubstituted Bambusurils: Post-Macrocyclization Modification of Versatile Intermediates Havel, Václav Sadilová, Tereza Šindelář, Vladimír ACS Omega [Image: see text] A new bambusuril derivative, (H)BU[6], lacking substituents on the ureidic nitrogen atoms, has been isolated and characterized. This macrocycle was prepared by the deprotection of bambusuril (PMB)BU[6]. (H)BU[6] is attractive for use as a starting compound for the preparation of other bambusuril derivatives, which was demonstrated via propargylation and the copper-catalyzed click reaction performed on the macrocycle. American Chemical Society 2018-04-27 /pmc/articles/PMC6641224/ /pubmed/31458686 http://dx.doi.org/10.1021/acsomega.8b00497 Text en Copyright © 2018 American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.
spellingShingle Havel, Václav
Sadilová, Tereza
Šindelář, Vladimír
Unsubstituted Bambusurils: Post-Macrocyclization Modification of Versatile Intermediates
title Unsubstituted Bambusurils: Post-Macrocyclization Modification of Versatile Intermediates
title_full Unsubstituted Bambusurils: Post-Macrocyclization Modification of Versatile Intermediates
title_fullStr Unsubstituted Bambusurils: Post-Macrocyclization Modification of Versatile Intermediates
title_full_unstemmed Unsubstituted Bambusurils: Post-Macrocyclization Modification of Versatile Intermediates
title_short Unsubstituted Bambusurils: Post-Macrocyclization Modification of Versatile Intermediates
title_sort unsubstituted bambusurils: post-macrocyclization modification of versatile intermediates
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641224/
https://www.ncbi.nlm.nih.gov/pubmed/31458686
http://dx.doi.org/10.1021/acsomega.8b00497
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