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Periodic Trends Manifested through Gas-Phase Generation of Anions Such as [AlH(4)](−), [GaH(4)](−), [InH(4)](−), [SrH(3)](−), [BaH(3)](−), [Ba(0)(η(2)-O(2)CH)(1)](−), [Pb(0)H](−), [Bi(I)H(2)](−), and Bi(–) from Formates
[Image: see text] Metal-hydride anions of main group elements, such as BaH(3)(–) and InH(4)(–), were generated by dissociating formate adducts of the respective metal formates. Upon activation, these adducts fragment by formate-ion ejection or by decarboxylation. For adducts of alkali-metal formates...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641263/ https://www.ncbi.nlm.nih.gov/pubmed/31458596 http://dx.doi.org/10.1021/acsomega.7b01518 |