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To “Rollover” or Not? Stereoelectronically Guided C–H Functionalization Pathways from Rhodium–Abnormal NHC Intermediates
[Image: see text] Rollover C–H activation with transition-metal complexes has been found to be a difficult but viable pathway to functionalize potentially chelating molecules, which are otherwise reluctant to react further. However, selective rollover or nonrollover C–H activation pathway depends on...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641269/ https://www.ncbi.nlm.nih.gov/pubmed/31458483 http://dx.doi.org/10.1021/acsomega.7b01846 |