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Influence of Molecular Weight on Structure and Catalytic Characteristics of Ordered Mesoporous Carbon Derived from Lignin

[Image: see text] Bio-renewable lignin has been used as a carbon source for the preparation of porous carbon materials. Nevertheless, up to now, there are few studies about the influence of molecular weight of lignin on the structure and morphology of the ordered mesoporous carbon. Here, we synthesi...

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Autores principales: Qin, Hengfei, Jian, Ruihong, Bai, Jirong, Tang, Jianghong, Zhou, Yue, Zhu, Binglong, Zhao, Dejian, Ni, Zhijiang, Wang, Liangbiao, Liu, Weiqiao, Zhou, Quanfa, Li, Xi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641423/
https://www.ncbi.nlm.nih.gov/pubmed/31457970
http://dx.doi.org/10.1021/acsomega.7b01870
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author Qin, Hengfei
Jian, Ruihong
Bai, Jirong
Tang, Jianghong
Zhou, Yue
Zhu, Binglong
Zhao, Dejian
Ni, Zhijiang
Wang, Liangbiao
Liu, Weiqiao
Zhou, Quanfa
Li, Xi
author_facet Qin, Hengfei
Jian, Ruihong
Bai, Jirong
Tang, Jianghong
Zhou, Yue
Zhu, Binglong
Zhao, Dejian
Ni, Zhijiang
Wang, Liangbiao
Liu, Weiqiao
Zhou, Quanfa
Li, Xi
author_sort Qin, Hengfei
collection PubMed
description [Image: see text] Bio-renewable lignin has been used as a carbon source for the preparation of porous carbon materials. Nevertheless, up to now, there are few studies about the influence of molecular weight of lignin on the structure and morphology of the ordered mesoporous carbon. Here, we synthesized the ordered mesoporous carbon derived from different molecular weights of lignin and Pluronic F127. Fortunately, we found that molecular weight is an important factor for obtaining highly ordered channels, high specific surface area, and ordered mesoporous carbon. More importantly, the narrow well-defined mesoporous channel could exert a spatial restriction effect to some extent, which can serve as nanoreactors for efficient reactions and enhance catalytic performance. The highly ordered mesoporous carbon from lignin is a good candidate for Fischer–Tropsch synthesis catalyst supports.
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spelling pubmed-66414232019-08-27 Influence of Molecular Weight on Structure and Catalytic Characteristics of Ordered Mesoporous Carbon Derived from Lignin Qin, Hengfei Jian, Ruihong Bai, Jirong Tang, Jianghong Zhou, Yue Zhu, Binglong Zhao, Dejian Ni, Zhijiang Wang, Liangbiao Liu, Weiqiao Zhou, Quanfa Li, Xi ACS Omega [Image: see text] Bio-renewable lignin has been used as a carbon source for the preparation of porous carbon materials. Nevertheless, up to now, there are few studies about the influence of molecular weight of lignin on the structure and morphology of the ordered mesoporous carbon. Here, we synthesized the ordered mesoporous carbon derived from different molecular weights of lignin and Pluronic F127. Fortunately, we found that molecular weight is an important factor for obtaining highly ordered channels, high specific surface area, and ordered mesoporous carbon. More importantly, the narrow well-defined mesoporous channel could exert a spatial restriction effect to some extent, which can serve as nanoreactors for efficient reactions and enhance catalytic performance. The highly ordered mesoporous carbon from lignin is a good candidate for Fischer–Tropsch synthesis catalyst supports. American Chemical Society 2018-01-31 /pmc/articles/PMC6641423/ /pubmed/31457970 http://dx.doi.org/10.1021/acsomega.7b01870 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Qin, Hengfei
Jian, Ruihong
Bai, Jirong
Tang, Jianghong
Zhou, Yue
Zhu, Binglong
Zhao, Dejian
Ni, Zhijiang
Wang, Liangbiao
Liu, Weiqiao
Zhou, Quanfa
Li, Xi
Influence of Molecular Weight on Structure and Catalytic Characteristics of Ordered Mesoporous Carbon Derived from Lignin
title Influence of Molecular Weight on Structure and Catalytic Characteristics of Ordered Mesoporous Carbon Derived from Lignin
title_full Influence of Molecular Weight on Structure and Catalytic Characteristics of Ordered Mesoporous Carbon Derived from Lignin
title_fullStr Influence of Molecular Weight on Structure and Catalytic Characteristics of Ordered Mesoporous Carbon Derived from Lignin
title_full_unstemmed Influence of Molecular Weight on Structure and Catalytic Characteristics of Ordered Mesoporous Carbon Derived from Lignin
title_short Influence of Molecular Weight on Structure and Catalytic Characteristics of Ordered Mesoporous Carbon Derived from Lignin
title_sort influence of molecular weight on structure and catalytic characteristics of ordered mesoporous carbon derived from lignin
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641423/
https://www.ncbi.nlm.nih.gov/pubmed/31457970
http://dx.doi.org/10.1021/acsomega.7b01870
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