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Influence of Molecular Weight on Structure and Catalytic Characteristics of Ordered Mesoporous Carbon Derived from Lignin
[Image: see text] Bio-renewable lignin has been used as a carbon source for the preparation of porous carbon materials. Nevertheless, up to now, there are few studies about the influence of molecular weight of lignin on the structure and morphology of the ordered mesoporous carbon. Here, we synthesi...
Autores principales: | , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2018
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641423/ https://www.ncbi.nlm.nih.gov/pubmed/31457970 http://dx.doi.org/10.1021/acsomega.7b01870 |
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author | Qin, Hengfei Jian, Ruihong Bai, Jirong Tang, Jianghong Zhou, Yue Zhu, Binglong Zhao, Dejian Ni, Zhijiang Wang, Liangbiao Liu, Weiqiao Zhou, Quanfa Li, Xi |
author_facet | Qin, Hengfei Jian, Ruihong Bai, Jirong Tang, Jianghong Zhou, Yue Zhu, Binglong Zhao, Dejian Ni, Zhijiang Wang, Liangbiao Liu, Weiqiao Zhou, Quanfa Li, Xi |
author_sort | Qin, Hengfei |
collection | PubMed |
description | [Image: see text] Bio-renewable lignin has been used as a carbon source for the preparation of porous carbon materials. Nevertheless, up to now, there are few studies about the influence of molecular weight of lignin on the structure and morphology of the ordered mesoporous carbon. Here, we synthesized the ordered mesoporous carbon derived from different molecular weights of lignin and Pluronic F127. Fortunately, we found that molecular weight is an important factor for obtaining highly ordered channels, high specific surface area, and ordered mesoporous carbon. More importantly, the narrow well-defined mesoporous channel could exert a spatial restriction effect to some extent, which can serve as nanoreactors for efficient reactions and enhance catalytic performance. The highly ordered mesoporous carbon from lignin is a good candidate for Fischer–Tropsch synthesis catalyst supports. |
format | Online Article Text |
id | pubmed-6641423 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-66414232019-08-27 Influence of Molecular Weight on Structure and Catalytic Characteristics of Ordered Mesoporous Carbon Derived from Lignin Qin, Hengfei Jian, Ruihong Bai, Jirong Tang, Jianghong Zhou, Yue Zhu, Binglong Zhao, Dejian Ni, Zhijiang Wang, Liangbiao Liu, Weiqiao Zhou, Quanfa Li, Xi ACS Omega [Image: see text] Bio-renewable lignin has been used as a carbon source for the preparation of porous carbon materials. Nevertheless, up to now, there are few studies about the influence of molecular weight of lignin on the structure and morphology of the ordered mesoporous carbon. Here, we synthesized the ordered mesoporous carbon derived from different molecular weights of lignin and Pluronic F127. Fortunately, we found that molecular weight is an important factor for obtaining highly ordered channels, high specific surface area, and ordered mesoporous carbon. More importantly, the narrow well-defined mesoporous channel could exert a spatial restriction effect to some extent, which can serve as nanoreactors for efficient reactions and enhance catalytic performance. The highly ordered mesoporous carbon from lignin is a good candidate for Fischer–Tropsch synthesis catalyst supports. American Chemical Society 2018-01-31 /pmc/articles/PMC6641423/ /pubmed/31457970 http://dx.doi.org/10.1021/acsomega.7b01870 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Qin, Hengfei Jian, Ruihong Bai, Jirong Tang, Jianghong Zhou, Yue Zhu, Binglong Zhao, Dejian Ni, Zhijiang Wang, Liangbiao Liu, Weiqiao Zhou, Quanfa Li, Xi Influence of Molecular Weight on Structure and Catalytic Characteristics of Ordered Mesoporous Carbon Derived from Lignin |
title | Influence of Molecular Weight on Structure and Catalytic
Characteristics of Ordered Mesoporous Carbon Derived from Lignin |
title_full | Influence of Molecular Weight on Structure and Catalytic
Characteristics of Ordered Mesoporous Carbon Derived from Lignin |
title_fullStr | Influence of Molecular Weight on Structure and Catalytic
Characteristics of Ordered Mesoporous Carbon Derived from Lignin |
title_full_unstemmed | Influence of Molecular Weight on Structure and Catalytic
Characteristics of Ordered Mesoporous Carbon Derived from Lignin |
title_short | Influence of Molecular Weight on Structure and Catalytic
Characteristics of Ordered Mesoporous Carbon Derived from Lignin |
title_sort | influence of molecular weight on structure and catalytic
characteristics of ordered mesoporous carbon derived from lignin |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641423/ https://www.ncbi.nlm.nih.gov/pubmed/31457970 http://dx.doi.org/10.1021/acsomega.7b01870 |
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