Au-Catalyzed Hexannulation and Pt-Catalyzed Pentannulation of Propargylic Ester Bearing a 2-Alkynyl-phenyl Substituent: A Comparative DFT Study

[Image: see text] The mechanistic pathways of metal-catalyzed pentannulation and hexannulation of aromatic enediyne were studied quantum mechanically with Pt and Au salts. In agreement with the experimental facts, our result shows that the pentannulation favors over the hexannulation under Pt-cataly...

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Detalles Bibliográficos
Autores principales: Ghosh, Animesh, Basak, Atanu, Chakrabarty, Kuheli, Mondal, Sonjoy, Chatterjee, Arpita, Das, Gourab Kanti
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641497/
https://www.ncbi.nlm.nih.gov/pubmed/31457958
http://dx.doi.org/10.1021/acsomega.7b01889

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641497/
https://www.ncbi.nlm.nih.gov/pubmed/31457958
http://dx.doi.org/10.1021/acsomega.7b01889

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