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Readily Available Highly Active [Ti]-Adamantyl-BINOL Catalysts for the Enantioselective Alkylation of Aldehydes

[Image: see text] A series of enantiopure (R)-adamantyl 1,1′-binaphthalene-2,2′-diols were successfully synthesized in a straightforward one-step reaction from commercial products with excellent overall yields. The activity of chiral titanium catalyst derived from (R)-3,6,6′-tri(adamantan-1-yl)-[1,1...

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Detalles Bibliográficos
Autores principales: Navarro, Rodrigo, Monterde, Cristina, Iglesias, Marta, Sánchez, Félix
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641534/
https://www.ncbi.nlm.nih.gov/pubmed/31457961
http://dx.doi.org/10.1021/acsomega.7b02013

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