Mild Epoxidation of Allylic Alcohols Catalyzed by Titanium(III) Complexes: Selectivity and Mechanism

[Image: see text] A novel methodology for the epoxidation of a broad range of primary, secondary, and tertiary allylic alcohols is described using tert-butyl hydroperoxide as oxidant and Ti(III) species generated by reduction of Ti(IV) complexes, with manganese (0) in 1,4-dioxane under mild reaction...

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Detalles Bibliográficos
Autores principales: Botubol-Ares, José Manuel, Hanson, James R., Hernández-Galán, Rosario, Collado, Isidro G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641598/
https://www.ncbi.nlm.nih.gov/pubmed/31457640
http://dx.doi.org/10.1021/acsomega.7b00386

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641598/
https://www.ncbi.nlm.nih.gov/pubmed/31457640
http://dx.doi.org/10.1021/acsomega.7b00386

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