Solvent-Free Chemoselective Hydrogenation of Squalene to Squalane

[Image: see text] Squalene is selectively and entirely converted into squalane over the spherical sol–gel-entrapped Pd catalyst SiliaCat Pd(0) under solvent-free and mild reaction conditions of 3 bar H(2) and 70 °C. The catalyst was reused successfully in eight consecutive cycles, with palladium lea...

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Autores principales: Pandarus, Valerica, Ciriminna, Rosaria, Béland, François, Pagliaro, Mario, Kaliaguine, Serge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641624/
https://www.ncbi.nlm.nih.gov/pubmed/31457702
http://dx.doi.org/10.1021/acsomega.7b00625
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author Pandarus, Valerica
Ciriminna, Rosaria
Béland, François
Pagliaro, Mario
Kaliaguine, Serge
author_facet Pandarus, Valerica
Ciriminna, Rosaria
Béland, François
Pagliaro, Mario
Kaliaguine, Serge
author_sort Pandarus, Valerica
collection PubMed
description [Image: see text] Squalene is selectively and entirely converted into squalane over the spherical sol–gel-entrapped Pd catalyst SiliaCat Pd(0) under solvent-free and mild reaction conditions of 3 bar H(2) and 70 °C. The catalyst was reused successfully in eight consecutive cycles, with palladium leaching values <2 ppm, opening the route to sustainable and less-expensive hydrogenation of phytosqualene with important sustainability consequences.
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spelling pubmed-66416242019-08-27 Solvent-Free Chemoselective Hydrogenation of Squalene to Squalane Pandarus, Valerica Ciriminna, Rosaria Béland, François Pagliaro, Mario Kaliaguine, Serge ACS Omega [Image: see text] Squalene is selectively and entirely converted into squalane over the spherical sol–gel-entrapped Pd catalyst SiliaCat Pd(0) under solvent-free and mild reaction conditions of 3 bar H(2) and 70 °C. The catalyst was reused successfully in eight consecutive cycles, with palladium leaching values <2 ppm, opening the route to sustainable and less-expensive hydrogenation of phytosqualene with important sustainability consequences. American Chemical Society 2017-07-26 /pmc/articles/PMC6641624/ /pubmed/31457702 http://dx.doi.org/10.1021/acsomega.7b00625 Text en Copyright © 2017 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Pandarus, Valerica
Ciriminna, Rosaria
Béland, François
Pagliaro, Mario
Kaliaguine, Serge
Solvent-Free Chemoselective Hydrogenation of Squalene to Squalane
title Solvent-Free Chemoselective Hydrogenation of Squalene to Squalane
title_full Solvent-Free Chemoselective Hydrogenation of Squalene to Squalane
title_fullStr Solvent-Free Chemoselective Hydrogenation of Squalene to Squalane
title_full_unstemmed Solvent-Free Chemoselective Hydrogenation of Squalene to Squalane
title_short Solvent-Free Chemoselective Hydrogenation of Squalene to Squalane
title_sort solvent-free chemoselective hydrogenation of squalene to squalane
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641624/
https://www.ncbi.nlm.nih.gov/pubmed/31457702
http://dx.doi.org/10.1021/acsomega.7b00625
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