Temperature Distribution and Thermal Conductivity Measurements of Chirality-Assigned Single-Walled Carbon Nanotubes by Photoluminescence Imaging Spectroscopy

[Image: see text] It is expected that single-walled carbon nanotubes (SWCNTs) have high thermal conductivity along the tube axis and that the thermal conductivities depend on their structure, such as length, diameter, chirality (n, m), and so forth. Although many experimental measurements of the thermal conductivity have been reported, the SWCNT structure was not characterized sufficiently. In particular, the chirality was not assigned, and it was not confirmed whether SWCNT was isolated or not (bundled with multiplicate SWCNTs). Therefore, measured values widely vary (10(1) to 10(4) W/(m·K)) so far. Here, we measured the thermal conductivity of chirality-assigned SWCNTs, which were individually suspended, by using photoluminescence (PL) imaging spectroscopy. The temperature distribution along the tube axis was obtained, and the temperature dependence of the thermal conductivity was measured in a wide-temperature range (from 350 to 1000 K). For (9, 8) SWCNTs with 10–12 μm in length, the thermal conductivity was 1166 ± 243 W/(m·K) at 400 K. The proposed PL imaging spectroscopy enables to measure the thermal conductivity of SWCNTs with high precision and without any contacts, and it is an effective method in the temperature distribution measurements of nanomaterials.