Dimerization of Terminal Aryl Alkynes Catalyzed by Iron(II) Amine-Pyrazolyl Tripodal Complexes with E/Z Selectivity Controlled by tert-Butoxide

[Image: see text] The catalytic activity of iron(II) complexes with functionalized amine-pyrazolyl tripodal ligands toward dimerization of terminal alkynes in the presence a base (KO(t)Bu or NaO(t)Bu) has been studied. An unusual E/Z selectivity of the reaction determined by tert-butoxide was observ...

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Autores principales: Xue, Fei, Song, Xiaolu, Lin, Ting Ting, Munkerup, Kristin, Albawardi, Saad Fahad, Huang, Kuo-Wei, Hor, T. S. Andy, Zhao, Jin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641691/
https://www.ncbi.nlm.nih.gov/pubmed/31458721
http://dx.doi.org/10.1021/acsomega.8b00539
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author Xue, Fei
Song, Xiaolu
Lin, Ting Ting
Munkerup, Kristin
Albawardi, Saad Fahad
Huang, Kuo-Wei
Hor, T. S. Andy
Zhao, Jin
author_facet Xue, Fei
Song, Xiaolu
Lin, Ting Ting
Munkerup, Kristin
Albawardi, Saad Fahad
Huang, Kuo-Wei
Hor, T. S. Andy
Zhao, Jin
author_sort Xue, Fei
collection PubMed
description [Image: see text] The catalytic activity of iron(II) complexes with functionalized amine-pyrazolyl tripodal ligands toward dimerization of terminal alkynes in the presence a base (KO(t)Bu or NaO(t)Bu) has been studied. An unusual E/Z selectivity of the reaction determined by tert-butoxide was observed.
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spelling pubmed-66416912019-08-27 Dimerization of Terminal Aryl Alkynes Catalyzed by Iron(II) Amine-Pyrazolyl Tripodal Complexes with E/Z Selectivity Controlled by tert-Butoxide Xue, Fei Song, Xiaolu Lin, Ting Ting Munkerup, Kristin Albawardi, Saad Fahad Huang, Kuo-Wei Hor, T. S. Andy Zhao, Jin ACS Omega [Image: see text] The catalytic activity of iron(II) complexes with functionalized amine-pyrazolyl tripodal ligands toward dimerization of terminal alkynes in the presence a base (KO(t)Bu or NaO(t)Bu) has been studied. An unusual E/Z selectivity of the reaction determined by tert-butoxide was observed. American Chemical Society 2018-05-09 /pmc/articles/PMC6641691/ /pubmed/31458721 http://dx.doi.org/10.1021/acsomega.8b00539 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Xue, Fei
Song, Xiaolu
Lin, Ting Ting
Munkerup, Kristin
Albawardi, Saad Fahad
Huang, Kuo-Wei
Hor, T. S. Andy
Zhao, Jin
Dimerization of Terminal Aryl Alkynes Catalyzed by Iron(II) Amine-Pyrazolyl Tripodal Complexes with E/Z Selectivity Controlled by tert-Butoxide
title Dimerization of Terminal Aryl Alkynes Catalyzed by Iron(II) Amine-Pyrazolyl Tripodal Complexes with E/Z Selectivity Controlled by tert-Butoxide
title_full Dimerization of Terminal Aryl Alkynes Catalyzed by Iron(II) Amine-Pyrazolyl Tripodal Complexes with E/Z Selectivity Controlled by tert-Butoxide
title_fullStr Dimerization of Terminal Aryl Alkynes Catalyzed by Iron(II) Amine-Pyrazolyl Tripodal Complexes with E/Z Selectivity Controlled by tert-Butoxide
title_full_unstemmed Dimerization of Terminal Aryl Alkynes Catalyzed by Iron(II) Amine-Pyrazolyl Tripodal Complexes with E/Z Selectivity Controlled by tert-Butoxide
title_short Dimerization of Terminal Aryl Alkynes Catalyzed by Iron(II) Amine-Pyrazolyl Tripodal Complexes with E/Z Selectivity Controlled by tert-Butoxide
title_sort dimerization of terminal aryl alkynes catalyzed by iron(ii) amine-pyrazolyl tripodal complexes with e/z selectivity controlled by tert-butoxide
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641691/
https://www.ncbi.nlm.nih.gov/pubmed/31458721
http://dx.doi.org/10.1021/acsomega.8b00539
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