DFT Studies on the Mechanism of the Iridium-Catalyzed Formal [4 + 1] Cycloaddition of Biphenylene with Alkenes

[Image: see text] Recently, we reported an Ir-catalyzed formal [4 + 1] cycloaddition of biphenylenes with alkenes, which gave 9,9-disubstituted fluorenes in moderate to excellent yields. We proposed a reaction mechanism that involved the intermolecular insertion of alkenes, β-elimination, and intram...

Descripción completa

Detalles Bibliográficos
Autores principales: Takano, Hideaki, Sugimura, Natsuhiko, Kanyiva, Kyalo Stephen, Shibata, Takanori
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641719/
https://www.ncbi.nlm.nih.gov/pubmed/31457794
http://dx.doi.org/10.1021/acsomega.7b00403

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641719/
https://www.ncbi.nlm.nih.gov/pubmed/31457794
http://dx.doi.org/10.1021/acsomega.7b00403

Ejemplares similares