How Important Is the Metal–Semiconductor Contact for Schottky Barrier Transistors: A Case Study on Few-Layer Black Phosphorus?

[Image: see text] Black phosphorus (BP) is a recently rediscovered layered two-dimensional (2D) semiconductor with a direct band gap (0.35–2 eV), high hole mobility (300–5000 cm(2)/Vs), and transport anisotropy. In this paper, we systematically investigated the effects of metal–semiconductor interface/contacts on the performance of BP Schottky barrier transistors. First, a “clean” metal–BP contact is formed with boron nitride (BN) passivation. It is found that the contact resistance of the clean metal–BP contact is seven times less than the previously reported values. As a result, high-performance top-gate BP transistors show a record high ON-state drain current (I(on)) of 940 μA/μm. Second, BN tunneling barriers are formed at the source/drain contacts to help understand the abnormally high OFF-state drain current (I(off)) in devices with clean metal–BP contacts. This high I(off) is attributed to the electron tunneling current from the drain to the channel. Finally, the I(on)/I(off) of BP field-effect transistors can be significantly improved by using an asymmetric contact structure. By inserting a thin BN tunneling barrier at the drain side, I(off) is reduced by a factor of ∼120 with a cost of 20% reduction in I(on). This case study of contacts on BP reveals the importance of understanding the metal–semiconductor contacts for 2D Schottky barrier transistors in general.