Polymers of Limonene Oxide and Carbon Dioxide: Polycarbonates of the Solar Economy

[Image: see text] Limonene epoxide (1,2-limonene oxide) readily reacts with carbon dioxide inserted in a ring-opening copolymerization reaction and forms polycarbonates of exceptional chemical and physical properties. Both poly(limonene carbonate) and poly(limonene dicarbonate) can be synthesized us...

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Autores principales: Parrino, Francesco, Fidalgo, Alexandra, Palmisano, Leonardo, Ilharco, Laura M., Pagliaro, Mario, Ciriminna, Rosaria
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641970/
https://www.ncbi.nlm.nih.gov/pubmed/31458704
http://dx.doi.org/10.1021/acsomega.8b00644
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author Parrino, Francesco
Fidalgo, Alexandra
Palmisano, Leonardo
Ilharco, Laura M.
Pagliaro, Mario
Ciriminna, Rosaria
author_facet Parrino, Francesco
Fidalgo, Alexandra
Palmisano, Leonardo
Ilharco, Laura M.
Pagliaro, Mario
Ciriminna, Rosaria
author_sort Parrino, Francesco
collection PubMed
description [Image: see text] Limonene epoxide (1,2-limonene oxide) readily reacts with carbon dioxide inserted in a ring-opening copolymerization reaction and forms polycarbonates of exceptional chemical and physical properties. Both poly(limonene carbonate) and poly(limonene dicarbonate) can be synthesized using low-cost Zn or Al homogeneous catalysts. This study addresses selected relevant questions concerning the technical and economic feasibility of limonene and carbon dioxide polymers en route to the bioeconomy.
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spelling pubmed-66419702019-08-27 Polymers of Limonene Oxide and Carbon Dioxide: Polycarbonates of the Solar Economy Parrino, Francesco Fidalgo, Alexandra Palmisano, Leonardo Ilharco, Laura M. Pagliaro, Mario Ciriminna, Rosaria ACS Omega [Image: see text] Limonene epoxide (1,2-limonene oxide) readily reacts with carbon dioxide inserted in a ring-opening copolymerization reaction and forms polycarbonates of exceptional chemical and physical properties. Both poly(limonene carbonate) and poly(limonene dicarbonate) can be synthesized using low-cost Zn or Al homogeneous catalysts. This study addresses selected relevant questions concerning the technical and economic feasibility of limonene and carbon dioxide polymers en route to the bioeconomy. American Chemical Society 2018-05-03 /pmc/articles/PMC6641970/ /pubmed/31458704 http://dx.doi.org/10.1021/acsomega.8b00644 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Parrino, Francesco
Fidalgo, Alexandra
Palmisano, Leonardo
Ilharco, Laura M.
Pagliaro, Mario
Ciriminna, Rosaria
Polymers of Limonene Oxide and Carbon Dioxide: Polycarbonates of the Solar Economy
title Polymers of Limonene Oxide and Carbon Dioxide: Polycarbonates of the Solar Economy
title_full Polymers of Limonene Oxide and Carbon Dioxide: Polycarbonates of the Solar Economy
title_fullStr Polymers of Limonene Oxide and Carbon Dioxide: Polycarbonates of the Solar Economy
title_full_unstemmed Polymers of Limonene Oxide and Carbon Dioxide: Polycarbonates of the Solar Economy
title_short Polymers of Limonene Oxide and Carbon Dioxide: Polycarbonates of the Solar Economy
title_sort polymers of limonene oxide and carbon dioxide: polycarbonates of the solar economy
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641970/
https://www.ncbi.nlm.nih.gov/pubmed/31458704
http://dx.doi.org/10.1021/acsomega.8b00644
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