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Two Mercury Antimony Chalcogenides Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6) with Cesium Cations as Counterions

[Image: see text] Two novel layer structure compounds, Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6), were synthesized in organic solvent under solvothermal conditions. The Cs(2)HgSb(4)S(8) is formed of [HgSb(4)S(8)](2–) ribbons and S atoms by corner sharing. The Cs(2)Hg(2)Sb(2)Se(6) is made up of [SbHg...

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Autores principales: Du, Cui-Xia, Qi, Fei-Yan, Chen, Juan, Baiyin, Menghe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643381/
https://www.ncbi.nlm.nih.gov/pubmed/31458179
http://dx.doi.org/10.1021/acsomega.8b02059
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author Du, Cui-Xia
Qi, Fei-Yan
Chen, Juan
Baiyin, Menghe
author_facet Du, Cui-Xia
Qi, Fei-Yan
Chen, Juan
Baiyin, Menghe
author_sort Du, Cui-Xia
collection PubMed
description [Image: see text] Two novel layer structure compounds, Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6), were synthesized in organic solvent under solvothermal conditions. The Cs(2)HgSb(4)S(8) is formed of [HgSb(4)S(8)](2–) ribbons and S atoms by corner sharing. The Cs(2)Hg(2)Sb(2)Se(6) is made up of [SbHg(2)Se(6)](5–) ribbon and disorder trigonal-pyramidal SbSe(3) by sharing μ(3)-Se. These compounds are characterized by single-crystal X-ray diffraction, powder X-ray diffraction, solid-state optical absorption spectra, and so on.
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spelling pubmed-66433812019-08-27 Two Mercury Antimony Chalcogenides Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6) with Cesium Cations as Counterions Du, Cui-Xia Qi, Fei-Yan Chen, Juan Baiyin, Menghe ACS Omega [Image: see text] Two novel layer structure compounds, Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6), were synthesized in organic solvent under solvothermal conditions. The Cs(2)HgSb(4)S(8) is formed of [HgSb(4)S(8)](2–) ribbons and S atoms by corner sharing. The Cs(2)Hg(2)Sb(2)Se(6) is made up of [SbHg(2)Se(6)](5–) ribbon and disorder trigonal-pyramidal SbSe(3) by sharing μ(3)-Se. These compounds are characterized by single-crystal X-ray diffraction, powder X-ray diffraction, solid-state optical absorption spectra, and so on. American Chemical Society 2018-11-09 /pmc/articles/PMC6643381/ /pubmed/31458179 http://dx.doi.org/10.1021/acsomega.8b02059 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Du, Cui-Xia
Qi, Fei-Yan
Chen, Juan
Baiyin, Menghe
Two Mercury Antimony Chalcogenides Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6) with Cesium Cations as Counterions
title Two Mercury Antimony Chalcogenides Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6) with Cesium Cations as Counterions
title_full Two Mercury Antimony Chalcogenides Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6) with Cesium Cations as Counterions
title_fullStr Two Mercury Antimony Chalcogenides Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6) with Cesium Cations as Counterions
title_full_unstemmed Two Mercury Antimony Chalcogenides Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6) with Cesium Cations as Counterions
title_short Two Mercury Antimony Chalcogenides Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6) with Cesium Cations as Counterions
title_sort two mercury antimony chalcogenides cs(2)hgsb(4)s(8) and cs(2)hg(2)sb(2)se(6) with cesium cations as counterions
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643381/
https://www.ncbi.nlm.nih.gov/pubmed/31458179
http://dx.doi.org/10.1021/acsomega.8b02059
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