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Two Mercury Antimony Chalcogenides Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6) with Cesium Cations as Counterions
[Image: see text] Two novel layer structure compounds, Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6), were synthesized in organic solvent under solvothermal conditions. The Cs(2)HgSb(4)S(8) is formed of [HgSb(4)S(8)](2–) ribbons and S atoms by corner sharing. The Cs(2)Hg(2)Sb(2)Se(6) is made up of [SbHg...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2018
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643381/ https://www.ncbi.nlm.nih.gov/pubmed/31458179 http://dx.doi.org/10.1021/acsomega.8b02059 |
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author | Du, Cui-Xia Qi, Fei-Yan Chen, Juan Baiyin, Menghe |
author_facet | Du, Cui-Xia Qi, Fei-Yan Chen, Juan Baiyin, Menghe |
author_sort | Du, Cui-Xia |
collection | PubMed |
description | [Image: see text] Two novel layer structure compounds, Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6), were synthesized in organic solvent under solvothermal conditions. The Cs(2)HgSb(4)S(8) is formed of [HgSb(4)S(8)](2–) ribbons and S atoms by corner sharing. The Cs(2)Hg(2)Sb(2)Se(6) is made up of [SbHg(2)Se(6)](5–) ribbon and disorder trigonal-pyramidal SbSe(3) by sharing μ(3)-Se. These compounds are characterized by single-crystal X-ray diffraction, powder X-ray diffraction, solid-state optical absorption spectra, and so on. |
format | Online Article Text |
id | pubmed-6643381 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-66433812019-08-27 Two Mercury Antimony Chalcogenides Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6) with Cesium Cations as Counterions Du, Cui-Xia Qi, Fei-Yan Chen, Juan Baiyin, Menghe ACS Omega [Image: see text] Two novel layer structure compounds, Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6), were synthesized in organic solvent under solvothermal conditions. The Cs(2)HgSb(4)S(8) is formed of [HgSb(4)S(8)](2–) ribbons and S atoms by corner sharing. The Cs(2)Hg(2)Sb(2)Se(6) is made up of [SbHg(2)Se(6)](5–) ribbon and disorder trigonal-pyramidal SbSe(3) by sharing μ(3)-Se. These compounds are characterized by single-crystal X-ray diffraction, powder X-ray diffraction, solid-state optical absorption spectra, and so on. American Chemical Society 2018-11-09 /pmc/articles/PMC6643381/ /pubmed/31458179 http://dx.doi.org/10.1021/acsomega.8b02059 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Du, Cui-Xia Qi, Fei-Yan Chen, Juan Baiyin, Menghe Two Mercury Antimony Chalcogenides Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6) with Cesium Cations as Counterions |
title | Two Mercury Antimony Chalcogenides Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6) with Cesium Cations as Counterions |
title_full | Two Mercury Antimony Chalcogenides Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6) with Cesium Cations as Counterions |
title_fullStr | Two Mercury Antimony Chalcogenides Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6) with Cesium Cations as Counterions |
title_full_unstemmed | Two Mercury Antimony Chalcogenides Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6) with Cesium Cations as Counterions |
title_short | Two Mercury Antimony Chalcogenides Cs(2)HgSb(4)S(8) and Cs(2)Hg(2)Sb(2)Se(6) with Cesium Cations as Counterions |
title_sort | two mercury antimony chalcogenides cs(2)hgsb(4)s(8) and cs(2)hg(2)sb(2)se(6) with cesium cations as counterions |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643381/ https://www.ncbi.nlm.nih.gov/pubmed/31458179 http://dx.doi.org/10.1021/acsomega.8b02059 |
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