Unveiling the Structure of MoS(x) Nanocrystals Produced upon Laser Fragmentation of MoS(2) Platelets

[Image: see text] Transition-metal dichalcogenide MoS(2) nanostructures have attracted tremendous attention due to their unique properties, which render them efficient nanoscale functional components for multiple applications ranging from sensors and biomedical probes to energy conversion and storage devices. However, despite the wide application range, the possibility to tune their size, shape, and composition is still a challenge. At the same time, the correlation of the structure with the optoelectronic properties is still unresolved. Here, we propose a new method to synthesize various morphologies of molybdenum sulfide nanocrystals, on the basis of ultrashort-pulsed laser fragmentation of MoS(2) platelets. Depending on the irradiation conditions, multiple MoS(x) morphologies in the form of nanoribbons, nanospheres, and photoluminescent quantum dots are obtained. Besides the detailed structural analysis of the various crystals formed, the structure–property relation is investigated and discussed.