Unanticipated Cleavage of 2-Nitrophenyl-Substituted N-Formyl Pyrazolines under Bechamp Conditions: Unveiling the Synthesis of 2-Aryl Quinolines and Their Mechanistic Exploration via DFT Studies

[Image: see text] We herein report for the first time an unusual decomposition of 2-nitrophenyl-substituted N-formyl pyrazolines under Bechamp reduction condition employed to yield 2-aryl quinolines exclusively instead of pyrazolo[1,5-c]quinazolines. The reaction investigation suggests acid-mediated...

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Detalles Bibliográficos
Autores principales: Joshi, Gaurav, Wani, Aabid Abdullah, Sharma, Sahil, Bhutani, Priyadeep, Bharatam, Prasad V., Paul, Atish T., Kumar, Raj
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643473/
https://www.ncbi.nlm.nih.gov/pubmed/31458441
http://dx.doi.org/10.1021/acsomega.8b02682

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