Alternating Copolymerization of Epoxides and Anhydrides Catalyzed by Aluminum Complexes

[Image: see text] The optimization of an organoaluminum catalytic system for the copolymerization of epoxides and anhydrides is presented. For this purpose, the influence of different variables in the process, such as catalysts, cocatalyst, solvent, or substrates, has been analyzed. Kinetic studies,...

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Detalles Bibliográficos
Autores principales: Martínez de Sarasa Buchaca, Marc, de la Cruz-Martínez, Felipe, Martínez, Javier, Alonso-Moreno, Carlos, Fernández-Baeza, Juan, Tejeda, Juan, Niza, Enrique, Castro-Osma, José A., Otero, Antonio, Lara-Sánchez, Agustín
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643587/
https://www.ncbi.nlm.nih.gov/pubmed/31458360
http://dx.doi.org/10.1021/acsomega.8b02759
Descripción
Sumario:[Image: see text] The optimization of an organoaluminum catalytic system for the copolymerization of epoxides and anhydrides is presented. For this purpose, the influence of different variables in the process, such as catalysts, cocatalyst, solvent, or substrates, has been analyzed. Kinetic studies, a proposal for the catalytic mechanism, and full characterization of the copolymers obtained are also discussed. Finally, a new copolymer, poly(limonene succinate), obtained by the optimized catalytic system is reported.

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