Alternating Copolymerization of Epoxides and Anhydrides Catalyzed by Aluminum Complexes

[Image: see text] The optimization of an organoaluminum catalytic system for the copolymerization of epoxides and anhydrides is presented. For this purpose, the influence of different variables in the process, such as catalysts, cocatalyst, solvent, or substrates, has been analyzed. Kinetic studies,...

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Autores principales: Martínez de Sarasa Buchaca, Marc, de la Cruz-Martínez, Felipe, Martínez, Javier, Alonso-Moreno, Carlos, Fernández-Baeza, Juan, Tejeda, Juan, Niza, Enrique, Castro-Osma, José A., Otero, Antonio, Lara-Sánchez, Agustín
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643587/
https://www.ncbi.nlm.nih.gov/pubmed/31458360
http://dx.doi.org/10.1021/acsomega.8b02759
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author Martínez de Sarasa Buchaca, Marc
de la Cruz-Martínez, Felipe
Martínez, Javier
Alonso-Moreno, Carlos
Fernández-Baeza, Juan
Tejeda, Juan
Niza, Enrique
Castro-Osma, José A.
Otero, Antonio
Lara-Sánchez, Agustín
author_facet Martínez de Sarasa Buchaca, Marc
de la Cruz-Martínez, Felipe
Martínez, Javier
Alonso-Moreno, Carlos
Fernández-Baeza, Juan
Tejeda, Juan
Niza, Enrique
Castro-Osma, José A.
Otero, Antonio
Lara-Sánchez, Agustín
author_sort Martínez de Sarasa Buchaca, Marc
collection PubMed
description [Image: see text] The optimization of an organoaluminum catalytic system for the copolymerization of epoxides and anhydrides is presented. For this purpose, the influence of different variables in the process, such as catalysts, cocatalyst, solvent, or substrates, has been analyzed. Kinetic studies, a proposal for the catalytic mechanism, and full characterization of the copolymers obtained are also discussed. Finally, a new copolymer, poly(limonene succinate), obtained by the optimized catalytic system is reported.
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spelling pubmed-66435872019-08-27 Alternating Copolymerization of Epoxides and Anhydrides Catalyzed by Aluminum Complexes Martínez de Sarasa Buchaca, Marc de la Cruz-Martínez, Felipe Martínez, Javier Alonso-Moreno, Carlos Fernández-Baeza, Juan Tejeda, Juan Niza, Enrique Castro-Osma, José A. Otero, Antonio Lara-Sánchez, Agustín ACS Omega [Image: see text] The optimization of an organoaluminum catalytic system for the copolymerization of epoxides and anhydrides is presented. For this purpose, the influence of different variables in the process, such as catalysts, cocatalyst, solvent, or substrates, has been analyzed. Kinetic studies, a proposal for the catalytic mechanism, and full characterization of the copolymers obtained are also discussed. Finally, a new copolymer, poly(limonene succinate), obtained by the optimized catalytic system is reported. American Chemical Society 2018-12-18 /pmc/articles/PMC6643587/ /pubmed/31458360 http://dx.doi.org/10.1021/acsomega.8b02759 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Martínez de Sarasa Buchaca, Marc
de la Cruz-Martínez, Felipe
Martínez, Javier
Alonso-Moreno, Carlos
Fernández-Baeza, Juan
Tejeda, Juan
Niza, Enrique
Castro-Osma, José A.
Otero, Antonio
Lara-Sánchez, Agustín
Alternating Copolymerization of Epoxides and Anhydrides Catalyzed by Aluminum Complexes
title Alternating Copolymerization of Epoxides and Anhydrides Catalyzed by Aluminum Complexes
title_full Alternating Copolymerization of Epoxides and Anhydrides Catalyzed by Aluminum Complexes
title_fullStr Alternating Copolymerization of Epoxides and Anhydrides Catalyzed by Aluminum Complexes
title_full_unstemmed Alternating Copolymerization of Epoxides and Anhydrides Catalyzed by Aluminum Complexes
title_short Alternating Copolymerization of Epoxides and Anhydrides Catalyzed by Aluminum Complexes
title_sort alternating copolymerization of epoxides and anhydrides catalyzed by aluminum complexes
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643587/
https://www.ncbi.nlm.nih.gov/pubmed/31458360
http://dx.doi.org/10.1021/acsomega.8b02759
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