Mechanism for Copper(II)-Mediated Disaggregation of a Porphyrin J-Aggregate

[Image: see text] J-aggregates of anionic meso-tetrakis(4-sulfonatophenyl)porphyrin form at intermediate pH (2.3–3.1) in the presence of NiSO(4) or ZnSO(4) (ionic strength, I.S. = 3.2 M). These aggregates convert to monomeric porphyrin units via metallation with copper(II) ions. The kinetics for the...

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Detalles Bibliográficos
Autores principales: Trapani, Mariachiara, Occhiuto, Ilaria G., Zagami, Roberto, De Luca, Giovanna, Castriciano, Maria A., Romeo, Andrea, Scolaro, Luigi Monsù, Pasternack, Robert F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643757/
https://www.ncbi.nlm.nih.gov/pubmed/31458447
http://dx.doi.org/10.1021/acsomega.8b02913

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643757/
https://www.ncbi.nlm.nih.gov/pubmed/31458447
http://dx.doi.org/10.1021/acsomega.8b02913

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