Iodo-Cycloisomerization of Aryl(indol-3-yl)methane-Tethered Propargyl Alcohols to 3-Iodocarbazoles via Selective 1,2-Alkyl Migration

[Image: see text] Herein, we disclose the first report on iodo-cycloisomerization of 1-(indol-3-yl)-1-arylbut-3-yn-2-ols to form 3-iodocarbazoles. The synthesis proceeds through a cascade 5-endo-spirocyclization, followed by selective 1,2-alkyl migration. This method governs the green synthesis prin...

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Detalles Bibliográficos
Autores principales: Yaragorla, Srinivasarao, Bag, Debojyoti, Dada, Ravikrishna, Jose, K.V. Jovan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643784/
https://www.ncbi.nlm.nih.gov/pubmed/31458169
http://dx.doi.org/10.1021/acsomega.8b02393

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643784/
https://www.ncbi.nlm.nih.gov/pubmed/31458169
http://dx.doi.org/10.1021/acsomega.8b02393

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