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Substituent Effects on the Electrochemistry and Electronic Coupling of Terphenyl-Bridged Cyclometalated Ruthenium–Amine Conjugated Complexes

[Image: see text] Six terphenyl-bridged cyclometalated ruthenium–amine conjugated complexes 4(PF(6))–9(PF(6)) were synthesized and studied. Three different substituents, methoxy, methyl, and chloro, were used to vary the electronic nature of the amine unit, and two terminal ligands 2,2′:6′,2″-terpyr...

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Detalles Bibliográficos
Autores principales: Li, Zhi-Juan, Shen, Jun-Jian, Shao, Jiang-Yang, Zhong, Yu-Wu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643824/
https://www.ncbi.nlm.nih.gov/pubmed/31458305
http://dx.doi.org/10.1021/acsomega.8b03058