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Storage of Methane Gas in the Form of Clathrates in the Presence of Natural Bioadditives

[Image: see text] Methane (CH(4)) and carbon dioxide (CO(2)), the important greenhouse gases, are capable of forming clathrate hydrates under some suitable thermodynamic conditions. The gas storage capacity of these materials is high, and therefore they are often useful in gas storage applications....

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Autores principales: Kiran, Burla Sai, Prasad, Pinnelli S. R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643833/
https://www.ncbi.nlm.nih.gov/pubmed/31458463
http://dx.doi.org/10.1021/acsomega.8b03097
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author Kiran, Burla Sai
Prasad, Pinnelli S. R.
author_facet Kiran, Burla Sai
Prasad, Pinnelli S. R.
author_sort Kiran, Burla Sai
collection PubMed
description [Image: see text] Methane (CH(4)) and carbon dioxide (CO(2)), the important greenhouse gases, are capable of forming clathrate hydrates under some suitable thermodynamic conditions. The gas storage capacity of these materials is high, and therefore they are often useful in gas storage applications. Certain expensive and toxic chemicals are employed to accelerate/decelerate the process. In this study, we report rapid (∼30–50 min) and effective (∼80%) methane hydrate conversion in the presence of three naturally occurring additives such as dry powders from Nelumbo nucifera (Indian lotus), Piper betle (betel), and Azadirachta indica (neem), at lower concentrations (0.5 wt %). Obtained results were carefully compared with the well-known kinetic promoter (sodium dodecyl sulfate). All the biomaterials are equally good kinetic promoters for methane hydrates, although the required subcooling is significantly large. However, no hydrate formation is observed with CO(2) gas.
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spelling pubmed-66438332019-08-27 Storage of Methane Gas in the Form of Clathrates in the Presence of Natural Bioadditives Kiran, Burla Sai Prasad, Pinnelli S. R. ACS Omega [Image: see text] Methane (CH(4)) and carbon dioxide (CO(2)), the important greenhouse gases, are capable of forming clathrate hydrates under some suitable thermodynamic conditions. The gas storage capacity of these materials is high, and therefore they are often useful in gas storage applications. Certain expensive and toxic chemicals are employed to accelerate/decelerate the process. In this study, we report rapid (∼30–50 min) and effective (∼80%) methane hydrate conversion in the presence of three naturally occurring additives such as dry powders from Nelumbo nucifera (Indian lotus), Piper betle (betel), and Azadirachta indica (neem), at lower concentrations (0.5 wt %). Obtained results were carefully compared with the well-known kinetic promoter (sodium dodecyl sulfate). All the biomaterials are equally good kinetic promoters for methane hydrates, although the required subcooling is significantly large. However, no hydrate formation is observed with CO(2) gas. American Chemical Society 2018-12-31 /pmc/articles/PMC6643833/ /pubmed/31458463 http://dx.doi.org/10.1021/acsomega.8b03097 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Kiran, Burla Sai
Prasad, Pinnelli S. R.
Storage of Methane Gas in the Form of Clathrates in the Presence of Natural Bioadditives
title Storage of Methane Gas in the Form of Clathrates in the Presence of Natural Bioadditives
title_full Storage of Methane Gas in the Form of Clathrates in the Presence of Natural Bioadditives
title_fullStr Storage of Methane Gas in the Form of Clathrates in the Presence of Natural Bioadditives
title_full_unstemmed Storage of Methane Gas in the Form of Clathrates in the Presence of Natural Bioadditives
title_short Storage of Methane Gas in the Form of Clathrates in the Presence of Natural Bioadditives
title_sort storage of methane gas in the form of clathrates in the presence of natural bioadditives
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643833/
https://www.ncbi.nlm.nih.gov/pubmed/31458463
http://dx.doi.org/10.1021/acsomega.8b03097
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