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Cationic Gemini Surfactants with a Bipyridyl Spacer as Corrosion Inhibitors for Carbon Steel
[Image: see text] In this work, cationic Gemini surfactants with different alkyl chain lengths (n = 8, 10, and 12) and a bipyridyl spacer were synthesized and tested as corrosion inhibitors for carbon steel in 1 M HCl solution. The corrosion inhibition efficiency was determined by weight loss measur...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2018
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643845/ https://www.ncbi.nlm.nih.gov/pubmed/31458464 http://dx.doi.org/10.1021/acsomega.8b03043 |
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author | Feng, Liwei Yin, Chengxian Zhang, Huali Li, Yufei Song, Xuehua Chen, Qibin Liu, Honglai |
author_facet | Feng, Liwei Yin, Chengxian Zhang, Huali Li, Yufei Song, Xuehua Chen, Qibin Liu, Honglai |
author_sort | Feng, Liwei |
collection | PubMed |
description | [Image: see text] In this work, cationic Gemini surfactants with different alkyl chain lengths (n = 8, 10, and 12) and a bipyridyl spacer were synthesized and tested as corrosion inhibitors for carbon steel in 1 M HCl solution. The corrosion inhibition efficiency was determined by weight loss measurement, potentiodynamic polarization, and electrochemical impedance spectroscopy. Results showed that such three inhibitors could effectively inhibit the corrosion of carbon steel in 1 M HCl solution, especially at their low concentrations, while the carbon chain length of Geminis used played a negligible role in the inhibition efficiency. Scanning electron microscopy/energy dispersive X-ray analysis observations demonstrated the formation of a protective inhibitor layer on the carbon steel surface. Additionally, the adsorption of the inhibitor molecules on the carbon steel surface was found to obey the Langmuir isotherm. |
format | Online Article Text |
id | pubmed-6643845 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-66438452019-08-27 Cationic Gemini Surfactants with a Bipyridyl Spacer as Corrosion Inhibitors for Carbon Steel Feng, Liwei Yin, Chengxian Zhang, Huali Li, Yufei Song, Xuehua Chen, Qibin Liu, Honglai ACS Omega [Image: see text] In this work, cationic Gemini surfactants with different alkyl chain lengths (n = 8, 10, and 12) and a bipyridyl spacer were synthesized and tested as corrosion inhibitors for carbon steel in 1 M HCl solution. The corrosion inhibition efficiency was determined by weight loss measurement, potentiodynamic polarization, and electrochemical impedance spectroscopy. Results showed that such three inhibitors could effectively inhibit the corrosion of carbon steel in 1 M HCl solution, especially at their low concentrations, while the carbon chain length of Geminis used played a negligible role in the inhibition efficiency. Scanning electron microscopy/energy dispersive X-ray analysis observations demonstrated the formation of a protective inhibitor layer on the carbon steel surface. Additionally, the adsorption of the inhibitor molecules on the carbon steel surface was found to obey the Langmuir isotherm. American Chemical Society 2018-12-31 /pmc/articles/PMC6643845/ /pubmed/31458464 http://dx.doi.org/10.1021/acsomega.8b03043 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Feng, Liwei Yin, Chengxian Zhang, Huali Li, Yufei Song, Xuehua Chen, Qibin Liu, Honglai Cationic Gemini Surfactants with a Bipyridyl Spacer as Corrosion Inhibitors for Carbon Steel |
title | Cationic Gemini Surfactants with a Bipyridyl Spacer
as Corrosion Inhibitors for Carbon Steel |
title_full | Cationic Gemini Surfactants with a Bipyridyl Spacer
as Corrosion Inhibitors for Carbon Steel |
title_fullStr | Cationic Gemini Surfactants with a Bipyridyl Spacer
as Corrosion Inhibitors for Carbon Steel |
title_full_unstemmed | Cationic Gemini Surfactants with a Bipyridyl Spacer
as Corrosion Inhibitors for Carbon Steel |
title_short | Cationic Gemini Surfactants with a Bipyridyl Spacer
as Corrosion Inhibitors for Carbon Steel |
title_sort | cationic gemini surfactants with a bipyridyl spacer
as corrosion inhibitors for carbon steel |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643845/ https://www.ncbi.nlm.nih.gov/pubmed/31458464 http://dx.doi.org/10.1021/acsomega.8b03043 |
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