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NiFe(2)O(4)/Poly(1,6-heptadiyne) Nanocomposite Energy-Storage Device for Electrical and Electronic Applications
[Image: see text] In present study, we have synthesized intrinsically conductive poly(1,6-heptadiynes) via cyclopolymerization technique, and further it is composited with the NiFe(2)O(4) to fabricate pellet for electrical and electronic applications. The synthesized polymer I–V characteristics were...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2018
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643917/ https://www.ncbi.nlm.nih.gov/pubmed/31458187 http://dx.doi.org/10.1021/acsomega.8b02306 |
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author | Magisetty, RaviPrakash Kumar, Pawan Kumar, Viresh Shukla, Anuj Kandasubramanian, Balasubramanian Shunmugam, Raja |
author_facet | Magisetty, RaviPrakash Kumar, Pawan Kumar, Viresh Shukla, Anuj Kandasubramanian, Balasubramanian Shunmugam, Raja |
author_sort | Magisetty, RaviPrakash |
collection | PubMed |
description | [Image: see text] In present study, we have synthesized intrinsically conductive poly(1,6-heptadiynes) via cyclopolymerization technique, and further it is composited with the NiFe(2)O(4) to fabricate pellet for electrical and electronic applications. The synthesized polymer I–V characteristics were obtained by two-probe measurement technique. The results suggest that the high current density of the synthesized polymer was in the range of 1.2 × 10(–5)–3.1 × 10(–5) S/cm, which attributes to the potentially induced hoping charge-carrier mechanism within the conjugated poly(1,6-heptadiynes). NiFe(2)O(4) and NiFe(2)O(4)/poly(1,6-heptadiynes) composite pellets were fabricated by utilizing hydraulic pelletizer. The sample’s electrical measurements were performed via broad-band dielectric impedance spectroscopy, wherein the composite permittivity was about ε = 45 (100 Hz to 10 kHz), which attributes to the NiFe(2)O(4) and poly(1,6-heptadiynes) phases; further, this describes the capacitance, which improved from 0.3 to 0.1 pf at 1 kHz. Also, these results suggest the reduced equivalent series resistance (72.1–1 MHz), which attributes to the incorporated intrinsically conducting poly(1,6-heptadiynes). Thus, the reduced dissipation factor (DF = 0.0032) was observed from impedance characteristics of a nanocomposite. Moreover, the improved Q-factor was observed, which was about 8.1–310 at 1 kHz. The resistance and capacitance time constant was also computed to be about 0.29 μs at 1 kHz for NiFe(2)O(4)/poly(1,6-heptadiynes) nanocomposite. Furthermore, the nanocomposite-enabled capacitor gravimetric energy density and power densities were calculated to be about 0.00575 mJ/g and 9.91 W/g, respectively. Additionally, thermal threatening, that is, heat generated within the capacitor, P(loss) is also estimated for the nanocomposite capacitor, which improved from 0.0006 to 8.9 × 10(–6), and these results suggest improved nanocomposite thermal stability. Further, the delineated quantities were compared to the commercially available configurations of tantalum hybrid capacitors and Al and Ta electrolytic capacitors, including carbon electrochemical capacitors, which suggest that the reported nanocomposites could be a suitable candidate for electrical and electronic applications. |
format | Online Article Text |
id | pubmed-6643917 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-66439172019-08-27 NiFe(2)O(4)/Poly(1,6-heptadiyne) Nanocomposite Energy-Storage Device for Electrical and Electronic Applications Magisetty, RaviPrakash Kumar, Pawan Kumar, Viresh Shukla, Anuj Kandasubramanian, Balasubramanian Shunmugam, Raja ACS Omega [Image: see text] In present study, we have synthesized intrinsically conductive poly(1,6-heptadiynes) via cyclopolymerization technique, and further it is composited with the NiFe(2)O(4) to fabricate pellet for electrical and electronic applications. The synthesized polymer I–V characteristics were obtained by two-probe measurement technique. The results suggest that the high current density of the synthesized polymer was in the range of 1.2 × 10(–5)–3.1 × 10(–5) S/cm, which attributes to the potentially induced hoping charge-carrier mechanism within the conjugated poly(1,6-heptadiynes). NiFe(2)O(4) and NiFe(2)O(4)/poly(1,6-heptadiynes) composite pellets were fabricated by utilizing hydraulic pelletizer. The sample’s electrical measurements were performed via broad-band dielectric impedance spectroscopy, wherein the composite permittivity was about ε = 45 (100 Hz to 10 kHz), which attributes to the NiFe(2)O(4) and poly(1,6-heptadiynes) phases; further, this describes the capacitance, which improved from 0.3 to 0.1 pf at 1 kHz. Also, these results suggest the reduced equivalent series resistance (72.1–1 MHz), which attributes to the incorporated intrinsically conducting poly(1,6-heptadiynes). Thus, the reduced dissipation factor (DF = 0.0032) was observed from impedance characteristics of a nanocomposite. Moreover, the improved Q-factor was observed, which was about 8.1–310 at 1 kHz. The resistance and capacitance time constant was also computed to be about 0.29 μs at 1 kHz for NiFe(2)O(4)/poly(1,6-heptadiynes) nanocomposite. Furthermore, the nanocomposite-enabled capacitor gravimetric energy density and power densities were calculated to be about 0.00575 mJ/g and 9.91 W/g, respectively. Additionally, thermal threatening, that is, heat generated within the capacitor, P(loss) is also estimated for the nanocomposite capacitor, which improved from 0.0006 to 8.9 × 10(–6), and these results suggest improved nanocomposite thermal stability. Further, the delineated quantities were compared to the commercially available configurations of tantalum hybrid capacitors and Al and Ta electrolytic capacitors, including carbon electrochemical capacitors, which suggest that the reported nanocomposites could be a suitable candidate for electrical and electronic applications. American Chemical Society 2018-11-12 /pmc/articles/PMC6643917/ /pubmed/31458187 http://dx.doi.org/10.1021/acsomega.8b02306 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Magisetty, RaviPrakash Kumar, Pawan Kumar, Viresh Shukla, Anuj Kandasubramanian, Balasubramanian Shunmugam, Raja NiFe(2)O(4)/Poly(1,6-heptadiyne) Nanocomposite Energy-Storage Device for Electrical and Electronic Applications |
title | NiFe(2)O(4)/Poly(1,6-heptadiyne)
Nanocomposite Energy-Storage
Device for Electrical and Electronic Applications |
title_full | NiFe(2)O(4)/Poly(1,6-heptadiyne)
Nanocomposite Energy-Storage
Device for Electrical and Electronic Applications |
title_fullStr | NiFe(2)O(4)/Poly(1,6-heptadiyne)
Nanocomposite Energy-Storage
Device for Electrical and Electronic Applications |
title_full_unstemmed | NiFe(2)O(4)/Poly(1,6-heptadiyne)
Nanocomposite Energy-Storage
Device for Electrical and Electronic Applications |
title_short | NiFe(2)O(4)/Poly(1,6-heptadiyne)
Nanocomposite Energy-Storage
Device for Electrical and Electronic Applications |
title_sort | nife(2)o(4)/poly(1,6-heptadiyne)
nanocomposite energy-storage
device for electrical and electronic applications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643917/ https://www.ncbi.nlm.nih.gov/pubmed/31458187 http://dx.doi.org/10.1021/acsomega.8b02306 |
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