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Pseudocapacitance of Mesoporous Spinel-Type MCo(2)O(4) (M = Co, Zn, and Ni) Rods Fabricated by a Facile Solvothermal Route
[Image: see text] We present the structural properties and electrochemical capacitance of mesoporous MCo(2)O(4) (M = Co, Zn, and Ni) rods synthesized by a facile solvothermal route without necessity to use templates. The Brunauer–Emmett–Teller specific surface areas of these mesoporous rods are foun...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2017
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644350/ https://www.ncbi.nlm.nih.gov/pubmed/31457852 http://dx.doi.org/10.1021/acsomega.7b00709 |
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author | Kumar, Vijay Mariappan, Chinnasamy Ramaraj Azmi, Raheleh Moock, Dominique Indris, Sylvio Bruns, Michael Ehrenberg, Helmut Vijaya Prakash, Gaddam |
author_facet | Kumar, Vijay Mariappan, Chinnasamy Ramaraj Azmi, Raheleh Moock, Dominique Indris, Sylvio Bruns, Michael Ehrenberg, Helmut Vijaya Prakash, Gaddam |
author_sort | Kumar, Vijay |
collection | PubMed |
description | [Image: see text] We present the structural properties and electrochemical capacitance of mesoporous MCo(2)O(4) (M = Co, Zn, and Ni) rods synthesized by a facile solvothermal route without necessity to use templates. The Brunauer–Emmett–Teller specific surface areas of these mesoporous rods are found to be about 24, 54, and 62 m(2) g(–1) with major pore diameters of about 31, 15, and 9 nm for MCo(2)O(4), M = Co, Zn, and Ni, respectively. X-ray photoelectron spectroscopy and X-ray diffraction studies reveal the phase purity of the samples with a predominant spinel-type crystal structure. The spinel crystal structure with lattice parameters of 8.118, 8.106, and 8.125 Å is obtained for MCo(2)O(4), M = Co, Zn, and Ni, respectively. The transmission electron microscopy study reveals that the mesoporous rods are built by self-assembled aggregates of nanoparticles which are well-interconnected to form stable mesoporous rods. The electrochemical capacitor performance was investigated by means of cyclic voltammetry, galvanostatic charge/discharge cycling, and impedance spectroscopy in a three-electrode configuration. As a result, the spinel-type MCo(2)O(4) rods exhibit high specific capacitances of 1846 F g(–1) (CoCo(2)O(4)), 1983 F g(–1) (ZnCo(2)O(4)), and 2118 F g(–1) (NiCo(2)O(4)) at a scan rate of 2 mV/s. Furthermore, the mesoporous spinel-type metal oxides show desirable stability in alkaline electrolyte during long-term cycling with excellent cycling efficiency. |
format | Online Article Text |
id | pubmed-6644350 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-66443502019-08-27 Pseudocapacitance of Mesoporous Spinel-Type MCo(2)O(4) (M = Co, Zn, and Ni) Rods Fabricated by a Facile Solvothermal Route Kumar, Vijay Mariappan, Chinnasamy Ramaraj Azmi, Raheleh Moock, Dominique Indris, Sylvio Bruns, Michael Ehrenberg, Helmut Vijaya Prakash, Gaddam ACS Omega [Image: see text] We present the structural properties and electrochemical capacitance of mesoporous MCo(2)O(4) (M = Co, Zn, and Ni) rods synthesized by a facile solvothermal route without necessity to use templates. The Brunauer–Emmett–Teller specific surface areas of these mesoporous rods are found to be about 24, 54, and 62 m(2) g(–1) with major pore diameters of about 31, 15, and 9 nm for MCo(2)O(4), M = Co, Zn, and Ni, respectively. X-ray photoelectron spectroscopy and X-ray diffraction studies reveal the phase purity of the samples with a predominant spinel-type crystal structure. The spinel crystal structure with lattice parameters of 8.118, 8.106, and 8.125 Å is obtained for MCo(2)O(4), M = Co, Zn, and Ni, respectively. The transmission electron microscopy study reveals that the mesoporous rods are built by self-assembled aggregates of nanoparticles which are well-interconnected to form stable mesoporous rods. The electrochemical capacitor performance was investigated by means of cyclic voltammetry, galvanostatic charge/discharge cycling, and impedance spectroscopy in a three-electrode configuration. As a result, the spinel-type MCo(2)O(4) rods exhibit high specific capacitances of 1846 F g(–1) (CoCo(2)O(4)), 1983 F g(–1) (ZnCo(2)O(4)), and 2118 F g(–1) (NiCo(2)O(4)) at a scan rate of 2 mV/s. Furthermore, the mesoporous spinel-type metal oxides show desirable stability in alkaline electrolyte during long-term cycling with excellent cycling efficiency. American Chemical Society 2017-09-20 /pmc/articles/PMC6644350/ /pubmed/31457852 http://dx.doi.org/10.1021/acsomega.7b00709 Text en Copyright © 2017 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Kumar, Vijay Mariappan, Chinnasamy Ramaraj Azmi, Raheleh Moock, Dominique Indris, Sylvio Bruns, Michael Ehrenberg, Helmut Vijaya Prakash, Gaddam Pseudocapacitance of Mesoporous Spinel-Type MCo(2)O(4) (M = Co, Zn, and Ni) Rods Fabricated by a Facile Solvothermal Route |
title | Pseudocapacitance of Mesoporous Spinel-Type MCo(2)O(4) (M = Co, Zn, and Ni) Rods Fabricated by a Facile
Solvothermal Route |
title_full | Pseudocapacitance of Mesoporous Spinel-Type MCo(2)O(4) (M = Co, Zn, and Ni) Rods Fabricated by a Facile
Solvothermal Route |
title_fullStr | Pseudocapacitance of Mesoporous Spinel-Type MCo(2)O(4) (M = Co, Zn, and Ni) Rods Fabricated by a Facile
Solvothermal Route |
title_full_unstemmed | Pseudocapacitance of Mesoporous Spinel-Type MCo(2)O(4) (M = Co, Zn, and Ni) Rods Fabricated by a Facile
Solvothermal Route |
title_short | Pseudocapacitance of Mesoporous Spinel-Type MCo(2)O(4) (M = Co, Zn, and Ni) Rods Fabricated by a Facile
Solvothermal Route |
title_sort | pseudocapacitance of mesoporous spinel-type mco(2)o(4) (m = co, zn, and ni) rods fabricated by a facile
solvothermal route |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644350/ https://www.ncbi.nlm.nih.gov/pubmed/31457852 http://dx.doi.org/10.1021/acsomega.7b00709 |
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