Concerted Functions of Surface Acid–Base Pairs and Supported Copper Catalysts for Dehydrogenative Synthesis of Esters from Primary Alcohols

[Image: see text] Dehydrogenative synthesis of esters from primary alcohols proceeded efficiently over a ZrO(2)-supported copper catalyst. A variety of esters were obtained from primary alcohols as well as diols in good to high yields. The key to the dehydrogenative synthesis of esters is the concer...

Descripción completa

Detalles Bibliográficos
Autores principales: Miura, Hiroki, Nakahara, Karin, Kitajima, Takahiro, Shishido, Tetsuya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644381/
https://www.ncbi.nlm.nih.gov/pubmed/31457863
http://dx.doi.org/10.1021/acsomega.7b01142
Descripción
Sumario:[Image: see text] Dehydrogenative synthesis of esters from primary alcohols proceeded efficiently over a ZrO(2)-supported copper catalyst. A variety of esters were obtained from primary alcohols as well as diols in good to high yields. The key to the dehydrogenative synthesis of esters is the concerted effect of the acid–base pairs on ZrO(2) and metallic copper.

Ejemplares similares