Concerted Functions of Surface Acid–Base Pairs and Supported Copper Catalysts for Dehydrogenative Synthesis of Esters from Primary Alcohols

[Image: see text] Dehydrogenative synthesis of esters from primary alcohols proceeded efficiently over a ZrO(2)-supported copper catalyst. A variety of esters were obtained from primary alcohols as well as diols in good to high yields. The key to the dehydrogenative synthesis of esters is the concer...

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Autores principales: Miura, Hiroki, Nakahara, Karin, Kitajima, Takahiro, Shishido, Tetsuya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644381/
https://www.ncbi.nlm.nih.gov/pubmed/31457863
http://dx.doi.org/10.1021/acsomega.7b01142
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author Miura, Hiroki
Nakahara, Karin
Kitajima, Takahiro
Shishido, Tetsuya
author_facet Miura, Hiroki
Nakahara, Karin
Kitajima, Takahiro
Shishido, Tetsuya
author_sort Miura, Hiroki
collection PubMed
description [Image: see text] Dehydrogenative synthesis of esters from primary alcohols proceeded efficiently over a ZrO(2)-supported copper catalyst. A variety of esters were obtained from primary alcohols as well as diols in good to high yields. The key to the dehydrogenative synthesis of esters is the concerted effect of the acid–base pairs on ZrO(2) and metallic copper.
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spelling pubmed-66443812019-08-27 Concerted Functions of Surface Acid–Base Pairs and Supported Copper Catalysts for Dehydrogenative Synthesis of Esters from Primary Alcohols Miura, Hiroki Nakahara, Karin Kitajima, Takahiro Shishido, Tetsuya ACS Omega [Image: see text] Dehydrogenative synthesis of esters from primary alcohols proceeded efficiently over a ZrO(2)-supported copper catalyst. A variety of esters were obtained from primary alcohols as well as diols in good to high yields. The key to the dehydrogenative synthesis of esters is the concerted effect of the acid–base pairs on ZrO(2) and metallic copper. American Chemical Society 2017-09-26 /pmc/articles/PMC6644381/ /pubmed/31457863 http://dx.doi.org/10.1021/acsomega.7b01142 Text en Copyright © 2017 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Miura, Hiroki
Nakahara, Karin
Kitajima, Takahiro
Shishido, Tetsuya
Concerted Functions of Surface Acid–Base Pairs and Supported Copper Catalysts for Dehydrogenative Synthesis of Esters from Primary Alcohols
title Concerted Functions of Surface Acid–Base Pairs and Supported Copper Catalysts for Dehydrogenative Synthesis of Esters from Primary Alcohols
title_full Concerted Functions of Surface Acid–Base Pairs and Supported Copper Catalysts for Dehydrogenative Synthesis of Esters from Primary Alcohols
title_fullStr Concerted Functions of Surface Acid–Base Pairs and Supported Copper Catalysts for Dehydrogenative Synthesis of Esters from Primary Alcohols
title_full_unstemmed Concerted Functions of Surface Acid–Base Pairs and Supported Copper Catalysts for Dehydrogenative Synthesis of Esters from Primary Alcohols
title_short Concerted Functions of Surface Acid–Base Pairs and Supported Copper Catalysts for Dehydrogenative Synthesis of Esters from Primary Alcohols
title_sort concerted functions of surface acid–base pairs and supported copper catalysts for dehydrogenative synthesis of esters from primary alcohols
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644381/
https://www.ncbi.nlm.nih.gov/pubmed/31457863
http://dx.doi.org/10.1021/acsomega.7b01142
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