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Synthesis of (Arylmido)niobium(V) Complexes Containing Ketimide, Phenoxide Ligands, and Some Reactions with Phenols and Alcohols
[Image: see text] Reactions of Nb(NAr)(N=C(t)Bu(2))(3) (3a, Ar = 2,6-Me(2)C(6)H(3)) with 1.0, 2.0, or 3.0 equiv of Ar′OH (Ar′ = 2,6-(i)Pr(2)C(6)H(3)) afforded Nb(NAr)(N=C(t)Bu(2))(2)(OAr′), Nb(NAr)(N=C(t)Bu(2))(OAr′)(2), or Nb(NAr)(OAr′)(3), respectively (at 25 °C), whereas the reaction with 2.0 equ...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644436/ https://www.ncbi.nlm.nih.gov/pubmed/31458800 http://dx.doi.org/10.1021/acsomega.8b01065 |