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Simple Preparation of Porous Carbon-Supported Ruthenium: Propitious Catalytic Activity in the Reduction of Ferrocyanate(III) and a Cationic Dye

[Image: see text] The present study involves the synthesis, characterization, and catalytic application of ruthenium nanoparticles (Ru NPs) supported on plastic-derived carbons (PDCs) synthesized from plastic wastes (soft drink bottles) as an alternative carbon source. PDCs have been further activat...

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Autores principales: Veerakumar, Pitchaimani, Salamalai, Kamaraj, Thanasekaran, Pounraj, Lin, King-Chuen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644444/
https://www.ncbi.nlm.nih.gov/pubmed/31457993
http://dx.doi.org/10.1021/acsomega.8b01680
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author Veerakumar, Pitchaimani
Salamalai, Kamaraj
Thanasekaran, Pounraj
Lin, King-Chuen
author_facet Veerakumar, Pitchaimani
Salamalai, Kamaraj
Thanasekaran, Pounraj
Lin, King-Chuen
author_sort Veerakumar, Pitchaimani
collection PubMed
description [Image: see text] The present study involves the synthesis, characterization, and catalytic application of ruthenium nanoparticles (Ru NPs) supported on plastic-derived carbons (PDCs) synthesized from plastic wastes (soft drink bottles) as an alternative carbon source. PDCs have been further activated with CO(2) and characterized by various analytical techniques. The catalytic activity of Ru@PDC for the reduction of potassium hexacyanoferrate(III), (K(3)[Fe(CN)(6)]), and new fuchsin (NF) dye by NaBH(4) was performed under mild conditions. The PDCs had spherical morphology with an average size of 0.5 μm, and the Ru NP (5 ± 0.2 nm) loading (4.01 wt %) into the PDC provided high catalytic performance for catalytic reduction of ferrocyanate(III) and NF dye. This catalyst can be recycled more than six times with only a minor loss of its catalytic activity. In addition, the stability and reusability of the Ru@PDC catalyst are also discussed.
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spelling pubmed-66444442019-08-27 Simple Preparation of Porous Carbon-Supported Ruthenium: Propitious Catalytic Activity in the Reduction of Ferrocyanate(III) and a Cationic Dye Veerakumar, Pitchaimani Salamalai, Kamaraj Thanasekaran, Pounraj Lin, King-Chuen ACS Omega [Image: see text] The present study involves the synthesis, characterization, and catalytic application of ruthenium nanoparticles (Ru NPs) supported on plastic-derived carbons (PDCs) synthesized from plastic wastes (soft drink bottles) as an alternative carbon source. PDCs have been further activated with CO(2) and characterized by various analytical techniques. The catalytic activity of Ru@PDC for the reduction of potassium hexacyanoferrate(III), (K(3)[Fe(CN)(6)]), and new fuchsin (NF) dye by NaBH(4) was performed under mild conditions. The PDCs had spherical morphology with an average size of 0.5 μm, and the Ru NP (5 ± 0.2 nm) loading (4.01 wt %) into the PDC provided high catalytic performance for catalytic reduction of ferrocyanate(III) and NF dye. This catalyst can be recycled more than six times with only a minor loss of its catalytic activity. In addition, the stability and reusability of the Ru@PDC catalyst are also discussed. American Chemical Society 2018-10-04 /pmc/articles/PMC6644444/ /pubmed/31457993 http://dx.doi.org/10.1021/acsomega.8b01680 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Veerakumar, Pitchaimani
Salamalai, Kamaraj
Thanasekaran, Pounraj
Lin, King-Chuen
Simple Preparation of Porous Carbon-Supported Ruthenium: Propitious Catalytic Activity in the Reduction of Ferrocyanate(III) and a Cationic Dye
title Simple Preparation of Porous Carbon-Supported Ruthenium: Propitious Catalytic Activity in the Reduction of Ferrocyanate(III) and a Cationic Dye
title_full Simple Preparation of Porous Carbon-Supported Ruthenium: Propitious Catalytic Activity in the Reduction of Ferrocyanate(III) and a Cationic Dye
title_fullStr Simple Preparation of Porous Carbon-Supported Ruthenium: Propitious Catalytic Activity in the Reduction of Ferrocyanate(III) and a Cationic Dye
title_full_unstemmed Simple Preparation of Porous Carbon-Supported Ruthenium: Propitious Catalytic Activity in the Reduction of Ferrocyanate(III) and a Cationic Dye
title_short Simple Preparation of Porous Carbon-Supported Ruthenium: Propitious Catalytic Activity in the Reduction of Ferrocyanate(III) and a Cationic Dye
title_sort simple preparation of porous carbon-supported ruthenium: propitious catalytic activity in the reduction of ferrocyanate(iii) and a cationic dye
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644444/
https://www.ncbi.nlm.nih.gov/pubmed/31457993
http://dx.doi.org/10.1021/acsomega.8b01680
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