Cargando…
Mechanistic Investigations of the Photochemical Isomerizations of [(CO)(5)MC(Me)(OMe)] (M = Cr, Mo, and W) Complexes
[Image: see text] The mechanisms for the photochemical isomerization reactions are determined theoretically using group 6 Fischer carbene complexes (CO)(5)M=C(Me)(OMe) (M = Cr, Mo, and W) and the complete-active-space self-consistent field (CASSCF) (10-orbital/8-electron active space) and second-ord...
| Autor principal: | |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2017
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644460/ https://www.ncbi.nlm.nih.gov/pubmed/31457808 http://dx.doi.org/10.1021/acsomega.7b00766 |