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Rationally Designed Circularly Arranged Sextuple Molecule with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide

[Image: see text] Herein, we report the design, synthesis, and cyanide-scavenging behavior of circularly arranged sextuple molecule 4. The six syringaldehyde units carrying equal number of dimethoxyphenolic moieties projecting at the periphery make the molecule highly efficient for cleaning up cyani...

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Autores principales: Singh, Palwinder, Kaur, Harpreet, Singh, Harpreet
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644536/
https://www.ncbi.nlm.nih.gov/pubmed/31458938
http://dx.doi.org/10.1021/acsomega.8b01155
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author Singh, Palwinder
Kaur, Harpreet
Singh, Harpreet
author_facet Singh, Palwinder
Kaur, Harpreet
Singh, Harpreet
author_sort Singh, Palwinder
collection PubMed
description [Image: see text] Herein, we report the design, synthesis, and cyanide-scavenging behavior of circularly arranged sextuple molecule 4. The six syringaldehyde units carrying equal number of dimethoxyphenolic moieties projecting at the periphery make the molecule highly efficient for cleaning up cyanide from the aqueous solution. The stoichiometric data 1:6 showed that six units of cyanide interact with one unit of compound 4. The association constant of the compound for cyanide was 2.5 × 10(4) M(–1), and its detection limit for cyanide was 10 nM. The compound was also found to remove cyanide bound to cytochrome c oxidase.
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spelling pubmed-66445362019-08-27 Rationally Designed Circularly Arranged Sextuple Molecule with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide Singh, Palwinder Kaur, Harpreet Singh, Harpreet ACS Omega [Image: see text] Herein, we report the design, synthesis, and cyanide-scavenging behavior of circularly arranged sextuple molecule 4. The six syringaldehyde units carrying equal number of dimethoxyphenolic moieties projecting at the periphery make the molecule highly efficient for cleaning up cyanide from the aqueous solution. The stoichiometric data 1:6 showed that six units of cyanide interact with one unit of compound 4. The association constant of the compound for cyanide was 2.5 × 10(4) M(–1), and its detection limit for cyanide was 10 nM. The compound was also found to remove cyanide bound to cytochrome c oxidase. American Chemical Society 2018-07-18 /pmc/articles/PMC6644536/ /pubmed/31458938 http://dx.doi.org/10.1021/acsomega.8b01155 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Singh, Palwinder
Kaur, Harpreet
Singh, Harpreet
Rationally Designed Circularly Arranged Sextuple Molecule with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide
title Rationally Designed Circularly Arranged Sextuple Molecule with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide
title_full Rationally Designed Circularly Arranged Sextuple Molecule with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide
title_fullStr Rationally Designed Circularly Arranged Sextuple Molecule with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide
title_full_unstemmed Rationally Designed Circularly Arranged Sextuple Molecule with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide
title_short Rationally Designed Circularly Arranged Sextuple Molecule with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide
title_sort rationally designed circularly arranged sextuple molecule with dimethoxyphenolic tentacles for ample hunting of cyanide
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644536/
https://www.ncbi.nlm.nih.gov/pubmed/31458938
http://dx.doi.org/10.1021/acsomega.8b01155
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