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Rationally Designed Circularly Arranged Sextuple Molecule with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide
[Image: see text] Herein, we report the design, synthesis, and cyanide-scavenging behavior of circularly arranged sextuple molecule 4. The six syringaldehyde units carrying equal number of dimethoxyphenolic moieties projecting at the periphery make the molecule highly efficient for cleaning up cyani...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2018
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644536/ https://www.ncbi.nlm.nih.gov/pubmed/31458938 http://dx.doi.org/10.1021/acsomega.8b01155 |
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author | Singh, Palwinder Kaur, Harpreet Singh, Harpreet |
author_facet | Singh, Palwinder Kaur, Harpreet Singh, Harpreet |
author_sort | Singh, Palwinder |
collection | PubMed |
description | [Image: see text] Herein, we report the design, synthesis, and cyanide-scavenging behavior of circularly arranged sextuple molecule 4. The six syringaldehyde units carrying equal number of dimethoxyphenolic moieties projecting at the periphery make the molecule highly efficient for cleaning up cyanide from the aqueous solution. The stoichiometric data 1:6 showed that six units of cyanide interact with one unit of compound 4. The association constant of the compound for cyanide was 2.5 × 10(4) M(–1), and its detection limit for cyanide was 10 nM. The compound was also found to remove cyanide bound to cytochrome c oxidase. |
format | Online Article Text |
id | pubmed-6644536 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-66445362019-08-27 Rationally Designed Circularly Arranged Sextuple Molecule with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide Singh, Palwinder Kaur, Harpreet Singh, Harpreet ACS Omega [Image: see text] Herein, we report the design, synthesis, and cyanide-scavenging behavior of circularly arranged sextuple molecule 4. The six syringaldehyde units carrying equal number of dimethoxyphenolic moieties projecting at the periphery make the molecule highly efficient for cleaning up cyanide from the aqueous solution. The stoichiometric data 1:6 showed that six units of cyanide interact with one unit of compound 4. The association constant of the compound for cyanide was 2.5 × 10(4) M(–1), and its detection limit for cyanide was 10 nM. The compound was also found to remove cyanide bound to cytochrome c oxidase. American Chemical Society 2018-07-18 /pmc/articles/PMC6644536/ /pubmed/31458938 http://dx.doi.org/10.1021/acsomega.8b01155 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Singh, Palwinder Kaur, Harpreet Singh, Harpreet Rationally Designed Circularly Arranged Sextuple Molecule with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide |
title | Rationally Designed Circularly Arranged Sextuple Molecule
with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide |
title_full | Rationally Designed Circularly Arranged Sextuple Molecule
with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide |
title_fullStr | Rationally Designed Circularly Arranged Sextuple Molecule
with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide |
title_full_unstemmed | Rationally Designed Circularly Arranged Sextuple Molecule
with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide |
title_short | Rationally Designed Circularly Arranged Sextuple Molecule
with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide |
title_sort | rationally designed circularly arranged sextuple molecule
with dimethoxyphenolic tentacles for ample hunting of cyanide |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644536/ https://www.ncbi.nlm.nih.gov/pubmed/31458938 http://dx.doi.org/10.1021/acsomega.8b01155 |
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