In Situ-Generated Niobium-Catalyzed Synthesis of 3-Pyrroline Derivatives via Ring-Closing Metathesis Reactions

[Image: see text] An active in situ-generated Nb complex was used as a catalyst in the ring-closing metathesis reaction of N,N-diallyl-p-toluenesulfonamide to afford the corresponding 3-pyrroline derivative. The Nb complex was formed from NbCl(5), trimethylsilyl chloride, Zn, and PhCHCl(2) in tetrah...

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Autores principales: Fuji, Maito, Chiwata, Jintaro, Ozaki, Makoto, Aratani, Shunsuke, Obora, Yasushi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644540/
https://www.ncbi.nlm.nih.gov/pubmed/31459018
http://dx.doi.org/10.1021/acsomega.8b01642
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author Fuji, Maito
Chiwata, Jintaro
Ozaki, Makoto
Aratani, Shunsuke
Obora, Yasushi
author_facet Fuji, Maito
Chiwata, Jintaro
Ozaki, Makoto
Aratani, Shunsuke
Obora, Yasushi
author_sort Fuji, Maito
collection PubMed
description [Image: see text] An active in situ-generated Nb complex was used as a catalyst in the ring-closing metathesis reaction of N,N-diallyl-p-toluenesulfonamide to afford the corresponding 3-pyrroline derivative. The Nb complex was formed from NbCl(5), trimethylsilyl chloride, Zn, and PhCHCl(2) in tetrahydrofuran. The Nb complex displayed high catalytic activity toward ring-closing metathesis reactions.
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spelling pubmed-66445402019-08-27 In Situ-Generated Niobium-Catalyzed Synthesis of 3-Pyrroline Derivatives via Ring-Closing Metathesis Reactions Fuji, Maito Chiwata, Jintaro Ozaki, Makoto Aratani, Shunsuke Obora, Yasushi ACS Omega [Image: see text] An active in situ-generated Nb complex was used as a catalyst in the ring-closing metathesis reaction of N,N-diallyl-p-toluenesulfonamide to afford the corresponding 3-pyrroline derivative. The Nb complex was formed from NbCl(5), trimethylsilyl chloride, Zn, and PhCHCl(2) in tetrahydrofuran. The Nb complex displayed high catalytic activity toward ring-closing metathesis reactions. American Chemical Society 2018-08-09 /pmc/articles/PMC6644540/ /pubmed/31459018 http://dx.doi.org/10.1021/acsomega.8b01642 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Fuji, Maito
Chiwata, Jintaro
Ozaki, Makoto
Aratani, Shunsuke
Obora, Yasushi
In Situ-Generated Niobium-Catalyzed Synthesis of 3-Pyrroline Derivatives via Ring-Closing Metathesis Reactions
title In Situ-Generated Niobium-Catalyzed Synthesis of 3-Pyrroline Derivatives via Ring-Closing Metathesis Reactions
title_full In Situ-Generated Niobium-Catalyzed Synthesis of 3-Pyrroline Derivatives via Ring-Closing Metathesis Reactions
title_fullStr In Situ-Generated Niobium-Catalyzed Synthesis of 3-Pyrroline Derivatives via Ring-Closing Metathesis Reactions
title_full_unstemmed In Situ-Generated Niobium-Catalyzed Synthesis of 3-Pyrroline Derivatives via Ring-Closing Metathesis Reactions
title_short In Situ-Generated Niobium-Catalyzed Synthesis of 3-Pyrroline Derivatives via Ring-Closing Metathesis Reactions
title_sort in situ-generated niobium-catalyzed synthesis of 3-pyrroline derivatives via ring-closing metathesis reactions
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644540/
https://www.ncbi.nlm.nih.gov/pubmed/31459018
http://dx.doi.org/10.1021/acsomega.8b01642
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