Aerobic Metal-Free Dioxygenation of Alkenes with tert-Butyl Nitrite and N-Hydroxylamines

[Image: see text] Metal-free dioxygenation of alkenes with tert-butyl nitrite and N-hydroxylamines (N-hydroxyphthalimide, N-hydroxybenzotriazole, and N-hydroxysuccinimide) is described to produce β-aminoxy nitrate esters using air as the oxidant. These organic nitrates can be readily converted into...

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Autores principales: Bag, Raghunath, Sar, Dinabandhu, Punniyamurthy, Tharmalingam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644589/
https://www.ncbi.nlm.nih.gov/pubmed/31457873
http://dx.doi.org/10.1021/acsomega.7b01111
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author Bag, Raghunath
Sar, Dinabandhu
Punniyamurthy, Tharmalingam
author_facet Bag, Raghunath
Sar, Dinabandhu
Punniyamurthy, Tharmalingam
author_sort Bag, Raghunath
collection PubMed
description [Image: see text] Metal-free dioxygenation of alkenes with tert-butyl nitrite and N-hydroxylamines (N-hydroxyphthalimide, N-hydroxybenzotriazole, and N-hydroxysuccinimide) is described to produce β-aminoxy nitrate esters using air as the oxidant. These organic nitrates can be readily converted into 1,2-diols and 1,2-diketone with broad substrate scope and functional group diversity.
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spelling pubmed-66445892019-08-27 Aerobic Metal-Free Dioxygenation of Alkenes with tert-Butyl Nitrite and N-Hydroxylamines Bag, Raghunath Sar, Dinabandhu Punniyamurthy, Tharmalingam ACS Omega [Image: see text] Metal-free dioxygenation of alkenes with tert-butyl nitrite and N-hydroxylamines (N-hydroxyphthalimide, N-hydroxybenzotriazole, and N-hydroxysuccinimide) is described to produce β-aminoxy nitrate esters using air as the oxidant. These organic nitrates can be readily converted into 1,2-diols and 1,2-diketone with broad substrate scope and functional group diversity. American Chemical Society 2017-09-29 /pmc/articles/PMC6644589/ /pubmed/31457873 http://dx.doi.org/10.1021/acsomega.7b01111 Text en Copyright © 2017 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Bag, Raghunath
Sar, Dinabandhu
Punniyamurthy, Tharmalingam
Aerobic Metal-Free Dioxygenation of Alkenes with tert-Butyl Nitrite and N-Hydroxylamines
title Aerobic Metal-Free Dioxygenation of Alkenes with tert-Butyl Nitrite and N-Hydroxylamines
title_full Aerobic Metal-Free Dioxygenation of Alkenes with tert-Butyl Nitrite and N-Hydroxylamines
title_fullStr Aerobic Metal-Free Dioxygenation of Alkenes with tert-Butyl Nitrite and N-Hydroxylamines
title_full_unstemmed Aerobic Metal-Free Dioxygenation of Alkenes with tert-Butyl Nitrite and N-Hydroxylamines
title_short Aerobic Metal-Free Dioxygenation of Alkenes with tert-Butyl Nitrite and N-Hydroxylamines
title_sort aerobic metal-free dioxygenation of alkenes with tert-butyl nitrite and n-hydroxylamines
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644589/
https://www.ncbi.nlm.nih.gov/pubmed/31457873
http://dx.doi.org/10.1021/acsomega.7b01111
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AT sardinabandhu aerobicmetalfreedioxygenationofalkeneswithtertbutylnitriteandnhydroxylamines
AT punniyamurthytharmalingam aerobicmetalfreedioxygenationofalkeneswithtertbutylnitriteandnhydroxylamines

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