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Fabrication of an Active Electronic Device Using a Hetero-bimetallic Coordination Polymer

[Image: see text] A nickel(II)/lead(II) coordination polymer [(NCS)Pb(H(2)O)LNi(NCS)](n) {H(2)L = N,N′-bis(3-methoxysalicylidene)propane-1,3-diamine} has been synthesized and characterized. The band gap (3.18 eV) calculated from Tauc’s plot suggests the semiconducting nature of the complex. The mate...

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Detalles Bibliográficos
Autores principales: Roy, Sourav, Halder, Soumi, Drew, Michael G. B., Ray, Partha Pratim, Chattopadhyay, Shouvik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644615/
https://www.ncbi.nlm.nih.gov/pubmed/31458004
http://dx.doi.org/10.1021/acsomega.8b02025
Descripción
Sumario:[Image: see text] A nickel(II)/lead(II) coordination polymer [(NCS)Pb(H(2)O)LNi(NCS)](n) {H(2)L = N,N′-bis(3-methoxysalicylidene)propane-1,3-diamine} has been synthesized and characterized. The band gap (3.18 eV) calculated from Tauc’s plot suggests the semiconducting nature of the complex. The material has a photosensitivity of 5.76, indicating its applicability in the fabrication of photosensitive devices. The complex has been successfully applied in a technologically challenging thin-film photosensitive Schottky device.