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Catalytic Conversion of Biomass-Derived 1,2-Propanediol to Propylene Oxide over Supported Solid-Base Catalysts
[Image: see text] A series of supported alkali metal salts were investigated as catalysts to produce propylene oxide (PO) from biomass-derived 1,2-propanediol via dehydrative epoxidation in a solid–gas reaction system. The effects of supports, cations, and anions in the alkali metal salts and calcin...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2018
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644628/ https://www.ncbi.nlm.nih.gov/pubmed/31459003 http://dx.doi.org/10.1021/acsomega.8b01121 |
Sumario: | [Image: see text] A series of supported alkali metal salts were investigated as catalysts to produce propylene oxide (PO) from biomass-derived 1,2-propanediol via dehydrative epoxidation in a solid–gas reaction system. The effects of supports, cations, and anions in the alkali metal salts and calcination temperature were investigated by X-ray diffraction and CO(2)-temperature-programmed desorption. The results indicate the catalysts with relative mild basicity having higher yields of PO. The highest yield of PO is 58.2% from reactions at 400 °C at an atmospheric pressure over KNO(3)/SiO(2). In addition, the catalyst could be reused after calcination in air at 550 °C. |
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