B(MIDA)-Containing Diborons

[Image: see text] Unsymmetrical B(MIDA)-containing diborons of potential synthetic utility were found to be synthesized from the readily available (neop)B–B(neop) and (HO)(2)B–B(OH)(2), and the procedure was extended to the generation of symmetrical (MIDA)B–B(MIDA). NMR and X-ray crystal structure s...

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Detalles Bibliográficos
Autores principales: Yoshida, Hiroto, Seki, Michinari, Kageyuki, Ikuo, Osaka, Itaru, Hatano, Sayaka, Abe, Manabu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644665/
https://www.ncbi.nlm.nih.gov/pubmed/31457845
http://dx.doi.org/10.1021/acsomega.7b01042
Descripción
Sumario:[Image: see text] Unsymmetrical B(MIDA)-containing diborons of potential synthetic utility were found to be synthesized from the readily available (neop)B–B(neop) and (HO)(2)B–B(OH)(2), and the procedure was extended to the generation of symmetrical (MIDA)B–B(MIDA). NMR and X-ray crystal structure studies revealed that B(MIDA) units of all of the diborons obtained in this study were in rigid tetrahedral environment.

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