B(MIDA)-Containing Diborons

[Image: see text] Unsymmetrical B(MIDA)-containing diborons of potential synthetic utility were found to be synthesized from the readily available (neop)B–B(neop) and (HO)(2)B–B(OH)(2), and the procedure was extended to the generation of symmetrical (MIDA)B–B(MIDA). NMR and X-ray crystal structure s...

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Autores principales: Yoshida, Hiroto, Seki, Michinari, Kageyuki, Ikuo, Osaka, Itaru, Hatano, Sayaka, Abe, Manabu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644665/
https://www.ncbi.nlm.nih.gov/pubmed/31457845
http://dx.doi.org/10.1021/acsomega.7b01042
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author Yoshida, Hiroto
Seki, Michinari
Kageyuki, Ikuo
Osaka, Itaru
Hatano, Sayaka
Abe, Manabu
author_facet Yoshida, Hiroto
Seki, Michinari
Kageyuki, Ikuo
Osaka, Itaru
Hatano, Sayaka
Abe, Manabu
author_sort Yoshida, Hiroto
collection PubMed
description [Image: see text] Unsymmetrical B(MIDA)-containing diborons of potential synthetic utility were found to be synthesized from the readily available (neop)B–B(neop) and (HO)(2)B–B(OH)(2), and the procedure was extended to the generation of symmetrical (MIDA)B–B(MIDA). NMR and X-ray crystal structure studies revealed that B(MIDA) units of all of the diborons obtained in this study were in rigid tetrahedral environment.
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spelling pubmed-66446652019-08-27 B(MIDA)-Containing Diborons Yoshida, Hiroto Seki, Michinari Kageyuki, Ikuo Osaka, Itaru Hatano, Sayaka Abe, Manabu ACS Omega [Image: see text] Unsymmetrical B(MIDA)-containing diborons of potential synthetic utility were found to be synthesized from the readily available (neop)B–B(neop) and (HO)(2)B–B(OH)(2), and the procedure was extended to the generation of symmetrical (MIDA)B–B(MIDA). NMR and X-ray crystal structure studies revealed that B(MIDA) units of all of the diborons obtained in this study were in rigid tetrahedral environment. American Chemical Society 2017-09-18 /pmc/articles/PMC6644665/ /pubmed/31457845 http://dx.doi.org/10.1021/acsomega.7b01042 Text en Copyright © 2017 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Yoshida, Hiroto
Seki, Michinari
Kageyuki, Ikuo
Osaka, Itaru
Hatano, Sayaka
Abe, Manabu
B(MIDA)-Containing Diborons
title B(MIDA)-Containing Diborons
title_full B(MIDA)-Containing Diborons
title_fullStr B(MIDA)-Containing Diborons
title_full_unstemmed B(MIDA)-Containing Diborons
title_short B(MIDA)-Containing Diborons
title_sort b(mida)-containing diborons
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644665/
https://www.ncbi.nlm.nih.gov/pubmed/31457845
http://dx.doi.org/10.1021/acsomega.7b01042
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AT hatanosayaka bmidacontainingdiborons
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